In:
Atmospheric Chemistry and Physics, Copernicus GmbH, Vol. 23, No. 7 ( 2023-04-14), p. 4559-4576
Abstract:
Abstract. Air ions are the key components for a series of atmospheric physicochemical
interactions, such as ion-catalyzed reactions, ion-molecule reactions, and
ion-induced new particle formation (NPF). They also control atmospheric electrical properties with effects on global climate. We performed molecular-level measurements of cluster ions at the high-altitude research station Chacaltaya (CHC; 5240 m a.s.l.), located in the Bolivian Andes, from January to May 2018 using an atmospheric-pressure-interface time-of-flight mass spectrometer. The negative ions mainly consisted of (H2SO4)0–3⚫HSO4-,
(HNO3)0–2⚫NO3-, SO5-,
(NH3)1–6⚫(H2SO4)3–7⚫HSO4-,
malonic-acid-derived, and CHO / CHON⚫(HSO4- / NO3-) cluster ions. Their temporal variability exhibited distinct diurnal and
seasonal patterns due to the changes in the corresponding neutral species'
molecular properties (such as electron affinity and proton affinity) and
concentrations resulting from the air masses arriving at CHC from different
source regions. The positive ions were mainly composed of protonated amines
and organic cluster ions but exhibited no clear diurnal variation. H2SO4–NH3 cluster ions likely contributed to the NPF process, particularly during the wet-to-dry transition period and the dry season, when CHC was more impacted by air masses originating from source regions with elevated SO2 emissions. Our study provides new insights into the chemical composition of atmospheric cluster ions and their role in new particle formation in the high-altitude mountain environment of the Bolivian Andes.
Type of Medium:
Online Resource
ISSN:
1680-7324
DOI:
10.5194/acp-23-4559-2023
DOI:
10.5194/acp-23-4559-2023-supplement
Language:
English
Publisher:
Copernicus GmbH
Publication Date:
2023
detail.hit.zdb_id:
2092549-9
detail.hit.zdb_id:
2069847-1