In:
Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 54, No. 11 ( 2005), p. 5246-
Kurzfassung:
A series of Er3(Fe, Co, M)29 (M=Cr, V, Ti, Mn, Ga, Nb) compounds has been synthesized and their structure and magnetic properties have been investigates by means of x-ray diffraction and magnetic measurements. It is found that the Fe-based Er3(Fe,M)29 compounds crystallize in the Th2Ni17-type structure with disordered substitution of the dumbbell Fe-Fe, instead of Nd3(Fe,Ti)29-type structure, so its chemical formula can also be expressed as Er2-n(Fe,M)17+2n (n=0.2). Substitution of M for Fe in the Er3Fe29 compound leads to an increase in the Curie temperature. With the substitution of Co for Fe in the Er3(Fe,M)29 (M=Cr, V) compounds, a new phase was found which crystallizes in monoclinic symmetry. The anisotropy of the Er3Fe19.5Co6V3.5 compound at room temperature is of easy-axis type and a spin reorientation transition from the easy-axis type to the easy-plane type anisotropy occurs when temperature decreases to 162K. A first order magnetization process (FOMP) was observed in the HMD magnetization curve of Er3Fe19.5Co6V3.5 at 5K, the critical field of the FOMP was derived to be 3.8T.
Materialart:
Online-Ressource
ISSN:
1000-3290
,
1000-3290
Sprache:
Unbekannt
Verlag:
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
Publikationsdatum:
2005