Format:
Online-Ressource
ISSN:
1521-3927
Content:
Abstract: New pyrrolo[3,4‐c]pyrrole‐1,4‐dione (DPP) derivatives carrying 3,4‐ethylenedioxy‐thiophenylphenyl (EDOT‐phenyl) substituent groups in the 3‐ and 6‐position, or in the 2‐ and 5‐position of the DPP chromophore were synthesised and electrochemically polymerised. The properties of the polymers were investigated using cyclic voltammetry and UV/Vis absorption spectroscopy. It was found that the optical and electronic properties differ greatly between the two polymers. Materials with EDOT‐phenyl groups in the 3‐ and 6‐positions represent conjugated polymers with a low oxidation potential and reversible electrochromic properties, whereas the polymer with EDOT‐phenyl groups in the 2‐ and 5‐positions is non‐conjugated and possesses a high oxidation potential and irreversible redox behaviour.
In:
volume:30
In:
number:21
In:
year:2009
In:
pages:1834-1840
In:
extent:7
In:
Macromolecular rapid communications, Weinheim : Wiley-VCH, 1980-, 30, Heft 21 (2009), 1834-1840 (gesamt 7), 1521-3927
Language:
English
DOI:
10.1002/marc.200900442
URN:
urn:nbn:de:101:1-2023042706165376038372
URL:
https://doi.org/10.1002/marc.200900442
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023042706165376038372
URL:
https://d-nb.info/1287139868/34
URL:
https://doi.org/10.1002/marc.200900442