Format:
Online-Ressource
ISSN:
1521-3862
Content:
Abstract: This paper describes partially fluorinated poly‐p‐xylylenes prepared by CVD polymerization. The synthesis, characterization, and surface modification of two partially fluorinated polymer coatings, namely poly (4,12‐dibromo‐1,1,9,9‐tetrafluoro‐p‐xylylene) (2) and poly (4‐heptadecafluorononanoyl‐p‐xylylene‐co‐p‐xylylene) (4), is described. Polymer 2 is synthesized from 4,12‐dibromo‐1,1,9,9‐tetrafluoro[2.2]paracyclophane (1), which is fluorinated at the aliphatic bridge, while 4‐heptadecafluorononanoyl[2.2]paracyclophane (3), which contains a perfluorinated keto group at the aromatic ring, is used to synthesize polymer 4. Furthermore, the keto‐functionalized polymer 4 introduces both extreme hydrophobicity and surface reactivity towards hydrazide‐containing ligands.
In:
volume:15
In:
number:4‐6
In:
year:2009
In:
pages:142-149
In:
extent:8
In:
Chemical vapor deposition, Weinheim : Wiley-VCH, 1995-2015, 15, Heft 4‐6 (2009), 142-149 (gesamt 8), 1521-3862
Language:
English
DOI:
10.1002/cvde.200806749
URN:
urn:nbn:de:101:1-2023051904470042859281
URL:
https://doi.org/10.1002/cvde.200806749
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023051904470042859281
URL:
https://d-nb.info/1289825785/34
URL:
https://doi.org/10.1002/cvde.200806749