Umfang:
Online-Ressource
ISSN:
1521-3765
Inhalt:
Abstract: The concept of “chemical reactivity” assumes that atoms and molecules contain the necessary information to describe their evolution over time as they transform from reactants to products. This concept was useful in the past to rationalize reactivity trends and predict the behavior of new systems. Free‐energy relationships have played a central role in this field. However, electronic effects often counter the energetic effects and give rise to “anomalies” or separate correlations. We discuss a quantification of the concept of “chemical reactivity”, emphasizing the role of molecular and electronic factors in Chemistry.
In:
volume:14
In:
number:22
In:
year:2008
In:
pages:6578-6587
In:
extent:10
In:
Chemistry - a European journal, Weinheim : Wiley-VCH, 1995-, 14, Heft 22 (2008), 6578-6587 (gesamt 10), 1521-3765
Sprache:
Englisch
DOI:
10.1002/chem.200701986
URN:
urn:nbn:de:101:1-2023072504542152103486
URL:
https://doi.org/10.1002/chem.200701986
URL:
https://nbn-resolving.org/urn:nbn:de:101:1-2023072504542152103486
URL:
https://d-nb.info/1297221591/34
URL:
https://doi.org/10.1002/chem.200701986
