Umfang:
Online Ressource (xi, 285 pages)
,
illustrations.
Ausgabe:
Online-Ausg. [S.l.] HathiTrust Digital Library Online-Ausg. [S.l.] : HathiTrust Digital Library
ISBN:
0444873945
,
9780444873941
,
9780080887425
,
0080887422
Serie:
Studies in surface science and catalysis vol. 45
Inhalt:
In this book the author presents an up-to-date summary of existing information on the structure, electronic properties, chemistry and catalytic properties of transition metal oxides. The subjects covered in the book can be divided into three sections. The first (chapters 1 to 3) covers the structural, physical, magnetic, and electronic properties of transition metal oxides. Although the emphasis is on surface properties, relevant bulk properties are also discussed. The second section (chapters 4 to 7) covers surface chemical properties. It includes topics that describe the importance of surface coordinative unsaturation in adsorption, the formation of surface acidity and the role of acidity in determining surface chemical properties, the nature and reactivities of adsorbed oxygen, and the surface chemistry in the reduction of oxides. The third section (chapters 8 to 14) is on the catalytic properties. Various catalytic reactions including decomposition, hydrogenation, isomerization, metathesis, selective oxidation, and reactions involving carbon oxides are discussed. Emphasis is placed more on reaction mechanisms and the role of catalysts than on kinetics and processes. Chapters on the preparation of oxide catalysts and on photo-assisted processes are also included. Whenever appropriate, relationships between various topics are indicated. Written for surface physicists, chemists, and catalytic engineers, the book will serve as a useful source of information for investigators and as a comprehensive overview of the subject for graduate students
Anmerkung:
Includes bibliographical references and index. - Print version record
,
Print version record
,
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002
,
Front Cover; Transition Metal Oxides: Surface Chemistry and Catalysis; Copyright Page; CONTENTS; PREFACE; Chapter 1. INTRODUCTION; References; Chapter 2. BULK AND SURFACE STRUCTURE OF TRANSITION METAL OXIDE; 2.1 Bulk Structure; 2.2 Shear Structure in Intermediate Oxides of Ti, V, and Mo; 2.3 Structure, Stability and Reconstruction of Oxide Surfaces; 2.4 Structure of Supported Oxides; References; Chapter 3. PHYSICAL AND ELECTRONIC PROPERTIES; 3.1 Surface Composition; 3.2 Ionicity of Oxides; 3.3 Magnetic Properties of Small Oxide Particles; 3.4 Quadrupole Splittings of Surface Ions
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3.5 Surface Electronic Structure3.6 Surface Vibration; References; Chapter 4. SURFACE COORDINATIVE UNSATURATION; 4.1 Formation of Surface Coordinative Unsaturation; 4.2 Chemical Properties of Surface Coordinatively Unsaturated Sites; 4.3 Adsorption of Small Molecules; References; Chapter 5. SURFACE ACIDITY; 5.1 Surface Acid Sites; 5.2 Formation of Surface Acid Sites; 5.3 Determination of Acidity; 5.4 Role of Acid Sites in Catalytic Reactions; References; Chapter 6. REDUCTION OF OXIDES; 6.1 Introduction; 6.2 Thermodynamics of Reduction; 6.3 Kinetic Models; 6.4 Mechanism of Reduction
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6.5 Effect of Support6.6 Effect of Other Components; 6.7 Reactivity of Reduced Surfaces; 6.8 Influence of Reduced Oxides on the Properties of Transition Metals; References; Chapter 7. OXYGEN ON OXIDES; 7.1 Nature of Adsorbed Oxygen; 7.2 Detection of Adsorbed Oxygen; 7.3 Reactivity of Adsorbed Oxygen; References; Chapter 8. PREPARATION OF OXIDES; 8.1 General Considerations; 8.2 Preparation of Unsupported Single Component Oxides; 8.3 Preparation of Supported Oxides; 8.4 Preparation of Multicomponent Oxides; References; Chapter 9. METATHESIS AND ISOMERIZATION; 9.1 Metathesis
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9.2 Isomenrization of AlkenesReferences; Chapter 10. DECOMPOSITION, HYDROGENATION AND RELATED REACTIONS; 10.1 Decomposition of Alcohols; 10.2 Decomposition of Nitrous Oxide; 10.3 Hydrogenation, H-D Exchange of Hydrocarbons, and H2-D2 Scrambling; 10.4 Reduction of NO; References; Chapter 11. SELECTIVE OXIDATION REACTIONS; 1 1.1 Introduction; 11.2 Types of Selective Oxidation Reactions; 11.3 Features of Catalytic Selective Oxidation; 11.4 Chemical Factors Affecting Selectivity; 1 1.5 Oxidation of Propene to Acrolein and Ammoxidation to Acrylonitrile; 11.6 Effect of Water on Propene Oxidation
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ReferencesChapter 12. SELECTIVE OXIDATION REACTIONS; 12.1 Selective Oxidation of Butenes; 12.2 Selective Oxidation of Butane; 12.3 Selective Oxidation of Methane; 12.4 Selective Oxidation of Methanol; References; Chapter 13. CATALTYIC REACTION BETWEEN HYDROGEN AND CARBON OXIDES 227; 13.1 Introduction; 13.2 Alcohol Synthesis on Copper-Zinc Oxide and Other Cu-based Catalysts; 13.3 Group VIII Metal/metal Oxide Catalysts; 13.4 Isosynthesis Reaction; 13.5 Water-Gas Shift Reaction; References; Chapter 14. PHOTO-ASSISTED SURFACE PROCESSES; 14.1 Introduction
,
14.2 Photo-Assisted Adsorption and Desorption
,
In this book the author presents an up-to-date summary of existing information on the structure, electronic properties, chemistry and catalytic properties of transition metal oxides. The subjects covered in the book can be divided into three sections. The first (chapters 1 to 3) covers the structural, physical, magnetic, and electronic properties of transition metal oxides. Although the emphasis is on surface properties, relevant bulk properties are also discussed. The second section (chapters 4 to 7) covers surface chemical properties. It includes topics that describe the importance of surface coordinative unsaturation in adsorption, the formation of surface acidity and the role of acidity in determining surface chemical properties, the nature and reactivities of adsorbed oxygen, and the surface chemistry in the reduction of oxides. The third section (chapters 8 to 14) is on the catalytic properties. Various catalytic reactions including decomposition, hydrogenation, isomerization, metathesis, selective oxidation, and reactions involving carbon oxides are discussed. Emphasis is placed more on reaction mechanisms and the role of catalysts than on kinetics and processes. Chapters on the preparation of oxide catalysts and on photo-assisted processes are also included. Whenever appropriate, relationships between various topics are indicated. Written for surface physicists, chemists, and catalytic engineers, the book will serve as a useful source of information for investigators and as a comprehensive overview of the subject for graduate students
,
Online-Ausg. [S.l.] : HathiTrust Digital Library
,
Master and use copy. Digital master created according to Benchmark for Faithful Digital Reproductions of Monographs and Serials, Version 1. Digital Library Federation, December 2002.
Weitere Ausg.:
0444873945
Weitere Ausg.:
Erscheint auch als Druck-Ausgabe Kung, Harold H Transition metal oxides Amsterdam, the Netherlands ; New York : Elsevier ; New York, NY, U.S.A. : Distributors for the U.S. and Canada, Elsevier Science Pub. Co., 1989
Weitere Ausg.:
Druckausg. Kung, Harold H. Transition metal oxides Amsterdam [u.a.] : Elsevier, 1989 0444873945
Sprache:
Englisch
Fachgebiete:
Chemie/Pharmazie
Schlagwort(e):
Katalyse
;
Übergangsmetalloxide
;
Oberfläche
;
Electronic books
;
Electronic books
