UID:
almafu_9960161360002883
Umfang:
1 online resource (465 pages)
ISBN:
9780128138359
,
0128138351
,
9780128138342
,
0128138343
Inhalt:
Reactivity of P-H Group of Phosphorus Based Compounds bridges the gap between inorganic and organic phosphorus compounds, providing a basis to explore the myriad possibilities for synthesis of novel low and high molecular phosphorus-containing compounds. It covers well-documented reactions in detail, including: tautomerization, oxidation, reduction, alkylation, oxidation coupling, addition reaction to: carbon-carbon multiple bonds, Schiff base, isocyanates, nitriles, epoxides; addition to carbonyl group, Kabachnik- Fields reaction, cross-coupling reaction and more. In an accessible style complete with synthetic routes and figures, the resource then covers the reactivity of multiple P-H group members: phosphines, phosphine oxides, hypophosphorus acid, H-phosphinic acids and polys(alkylene H-phosphonate). This valuable coverage supports the advancement of research and applications in this area for scientists solving a scientific problem or starting a variety of new projects, such as a new reaction for the synthesis of biologically active compounds, new methods of polymer synthesis or a new methodology for polymer modification.
Anmerkung:
Front Cover; Reactivity of P-H Group of Phosphorus Based Compounds; Copyright Page; Contents; About the Author; Preface; 1 Acidity and Tautomerization of P-H Group; 1.1 Acidity; 1.2 Tautomerization; 1.2.1 Tautomerization of Phosphine Oxides; 1.2.2 Tautomerization of Hypophosphorous Acid; 1.2.3 Tautomerization of H-Phosphinic Acid; 1.2.4 Tautomerization of H-Phosphonic Acid; References; 2 Reactivity of P-H Group of Phosphines; 2.1 Phosphine; 2.1.1 Methods for Preparation; 2.1.2 Reactivity of P-H Group; 2.1.2.1 Reaction with Metals; 2.1.2.2 Addition Reactions
,
2.1.2.2.1 Addition to Carbon-Carbon Multiple BondsRadical Addition; Nucleophilic Addition; Catalyzed Hydrophosphination; 2.1.2.2.2 Addition to Carbonyl Group; 2.1.2.3 Nucleophilic Substitution Reactions; 2.2 Primary Phosphines (RPH2); 2.2.1 Methods for Preparation; 2.2.2 Reactivity of P-H Group; 2.2.2.1 Addition Reactions; 2.2.2.1.1 Addition to Carbon-Carbon Multiple Bonds; 2.2.2.1.2 Addition to Carbonyl Group; 2.2.2.2 Cross-Coupling Reactions; 2.2.2.3 Cross-Dehydrogenative Coupling; 2.3 Primary Diphosphines; 2.3.1 Methods for Preparation; 2.3.2 Reactivity of P-H Group; 2.3.2.1 Metalation
,
2.5.2 Reactivity of P-H Group2.5.2.1 Condensation Reactions; 2.5.2.2 Cross-Coupling Reactions; 2.5.2.2.1 Diphenyldiphosphine PhHP-PHPh; 2.5.2.2.2 Tetraphenyldiphosphane; 2.6 Phosphine-Borane Complexes; 2.6.1 Phosphine-Borane; 2.6.1.1 Methods for Preparation; 2.6.2 Primary Phosphine-Boranes; 2.6.2.1 Methods for Preparation; 2.6.2.2 Reactivity of P-H Group; 2.6.2.2.1 Hydrophosphination; 2.6.2.2.2 Oxidative Addition; 2.6.2.2.3 Cross-Dehydrogenative Coupling; 2.6.2.2.4 Alkylation; 2.6.3 Secondary Phosphine-Boranes; 2.6.3.1 Methods for Preparation; 2.6.3.2 Reactivity of P-H Group
,
2.6.3.2.1 Alkylation2.6.3.2.2 Hydrophosphination; 2.6.3.2.3 Nucleophilic Substitutions; 2.6.3.2.4 Cross-Coupling Reactions; 2.6.3.2.5 Cross-Dehydrogenative Coupling; Poly(phosphinoborane)s; 2.7 Conclusion; References; 3 Reactivity of P-H Group of Phosphine Oxides; 3.1 Phosphine Oxide; 3.1.1 Methods for Preparation; 3.1.2 Reactivity of P-H Group; 3.2 Primary Phosphine Oxides; 3.2.1 Methods for Preparation; 3.2.2 Reactivity of P-H Group; 3.2.2.1 Dehydration; 3.2.2.2 Addition Reactions; 3.2.2.2.1 Addition to Carbon-Carbon Multiple Bonds; 3.3 Secondary Phosphine Oxides
Sprache:
Englisch
