UID:
almahu_9948026340902882
Umfang:
1 online resource (489 p.)
Ausgabe:
2nd ed.
ISBN:
1-281-05949-8
,
9786611059491
,
0-08-053797-9
Inhalt:
This book is a follow-up to Ivins Olefin Metathesis, (Academic Press, 1983). Bringing the standard text in the field up to date, this Second Edition is a result of rapid growth in the field, sparked by the discovery of numerous well-defined metal carbene complexes that can act as very efficient initiators of all types of olefin metathesis reaction, including ring-closing metathesis of acyclic dienes, enynes, and dienynes; ring-opening metathesis polymerizationof cycloalkenes, acyclic diene metathesis polymerization; and polymerization of alkynes, as well as simple olefin metathesis.
Anmerkung:
1983 ed., by K.J. Ivin, has title: Olefin metathesis.
,
Front Cover; Olefin Metathesis and Metathesis Polymerization; Copyright Page; Contents; Preface; Abbreviations; Chapter 1. Introduction; 1.1 The olefin metathesis reaction; 1.2 Brief history; 1.3 The metal carbene mechanism; 1.4 Equilibria and stereoselectivity; Chapter 2. Survey of catalyst systems; 2.1 Introduction; 2.2 Group IVA; 2.3 Group VA; 2.4 Group VIA; 2.5 Group VIIA; 2.6 Group VIII; 2.7 Photochemically activated catalysts; Chapter 3. The metal carbene/metallacyclobutane mechanism; 3.1 Introduction; 3.2 Evidence from cross-metathesis reactions
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3.3 Evidence from the stereochemistry of metathesis of internal olefins3.4 Evidence from ring-opening metathesis polymerization (ROMP); 3.5 Evidence from the reactions of well-defined metal carbene complexes; 3.6 Evidence from the reactions of metallacyclobutane complexes; 3.7 Evidence of initiating species in systems with non-carbene catalysts; 3.8 Theoretical treatments; Chapter 4. Related reactions; 4.1 Introduction; 4.2 [2 + 2] reactions between compounds containing multiple bonds; 4.3 Relationship to Ziegler-Natta polymerization
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4.4 Involvement of three-membered ring compounds in metathesis reactionsChapter 5. Ethene and terminal alkenes; 5.1 Introduction; 5.2 Ethene; 5.3 Propene; 5.4 But-1-ene and its derivatives; 5.5 Pent-1-ene and its derivatives; 5.6 Hex-1-ene and its derivatives; 5.7 Higher acyclic terminal alkenes; Chapter 6. Acyclic disubstituted and trisubstituted ethenes; 6.1 Introduction; 6.2 Cis/trans isomerization; 6.3 Pent-2-ene and 4-substituted derivatives; 6.4 Hex-2-ene and 4-methylhex-2-ene; 6.5 Hept-2-ene and hept-3-ene; 6.6 Higher acyclic internal olefins
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6.7 Stereoselectivity in the metathesis of acyclic olefins6.8 1,1-Disubstituted olefins; 6.9 Trisubstituted ethenes; Chapter 7. Acyclic functionalized alkenes; 7.1 Introduction; 7.2 Esters; 7.3 Other carbonyl-containing compounds; 7.4 Ethers; 7.5 Amines; 7.6 Nitriles; 7.7 Chlorides and bromides; 7.8 Sulfides and sulfonates; 7.9 Silanes and germanes; 7.10 Phosphanes; Chapter 8. Acyclic dienes; 8.1 Introduction; 8.2 Double bonds linked only by C atoms; 8.3 Double bonds linked by C and Si, Ge or Sn atoms; 8.4 Double bonds linked by C and N atoms; 8.5 Double bonds linked by C and O atoms
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8.6 Double bonds linked by C and P atoms8.7 Double bonds linked by C and S atoms; 8.8 Double bonds linked by C, Si, and O, or C, B and O atoms; 8.9 Divinylferrocene; 8.10 Some further applications in organic synthesis; 8.11 Copolymers by metathesis condensation; Chapter 9. Cross-metathesis between acyclic compounds; 9.1 Introduction; 9.2 Ethene; 9.3 Propene; 9.4 Butenes; 9.5 Pentenes; 9.6 Hexenes; 9.7 Higher olefins; 9.8 Functionalized olefins; Chapter 10. Acetylenes; 10.1 Introduction; 10.2 Metathesis reactions involving total cleavage of the C=C bond
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10.3 Metathesis reactions involving cleavage of two of the three C=C bonds
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English
Weitere Ausg.:
ISBN 0-12-377045-9
Sprache:
Englisch
