UID:
almafu_9960119885902883
Umfang:
1 online resource (xv, 175 pages) :
,
digital, PDF file(s).
ISBN:
0-511-73583-9
Inhalt:
When this book was first published in 1984, the discovery of laser-induced mutliphoton chemical reactions had led to a resurgence of interest in the theory of unimolecular reactions. Attempts to explain these phenomena had been built on a very imperfectly understood theory of thermal unimolecular reactions. In this book, Professor Pritchard presents a treatment that dissects the unimolecular reaction process into a sequence of distinct phases, so that the assumptions of the theory can be clearly seen, and confusion over the theory avoided. As such it provides a self-consistent foundation upon which to begin to treat these phenomena. Postgraduate students and research workers in physical chemistry will find this an invaluable textbook on a topic that has suddenly become of primary importance.
Anmerkung:
Title from publisher's bibliographic system (viewed on 05 Oct 2015).
,
1. The observed properties of thermal unimolecular reactions; 2. The master equation for internal relaxation in molecules; 3. Reaction as a perturbation of the internal relaxtion; 4. The specific rate function k(E) as an inverse Laplace transform; 5. Unimolecular fall-off in strong collision systems; 6. A molecular dynamic approach to specific rate functions; 7. Building in the randomisation processes; 8. Weak collision processes; 9. How well does it all work?; Appendix.
,
English
Weitere Ausg.:
ISBN 0-521-10586-2
Weitere Ausg.:
ISBN 0-521-25711-5
Sprache:
Englisch
URL:
https://doi.org/10.1017/CBO9780511735837
