UID:
almahu_9949198455702882
Umfang:
XI, 310 p.
,
online resource.
Ausgabe:
1st ed. 1998.
ISBN:
9789401149501
Anmerkung:
1 Diels-Alder reactions in aqueous media -- 1.1 Introduction -- 1.2 The effect of water on Diels-Alder reactivity -- 1.3 Regioselectivity and endo/exo-selectivity -- 1.4 Diastereofacial selectivity -- 1.5 Synthetic applications -- 1.6 Intramolecular cycloadditions -- References -- 2 Hetero Diels-Alder reactions -- 2.1 Introduction -- 2.2 Aza Diels-Alder reactions in aqueous media -- 2.3 Synthetic exploitation of the aqueous aza Diels-Alder reaction -- 2.4 Retro aza Diels-Alder reactions in aqueous media -- 3 -- References -- 3 Claisen rearrangements in aqueous solution -- 3.1 Introduction -- 3.2 Aromatic Claisen rearrangement -- 3.3 Aliphatic Claisen rearrangement -- 3.4 Synthetic exploitation of aqueous Claisen rearrangements -- 3.5 Water as a solvent -- 3.6 Multiparameter correlation-factor analyses -- 3.7 Other developments in Claisen rearrangements in aqueous solution -- 3.8 Summary -- Acknowledgements -- References -- 4 Carbonyl additions and organometallic chemistry in water -- 4.1 Introduction -- 4.2 Barbier-type alkylation reactions -- 4.3 Conjugate 1,4-additions -- 4.4 Cross-aldol and Reformatsky-type reactions -- 4.5 Pinacol coupling reactions -- 4.6 Miscellaneous reactions -- References -- 5 Aqueous transition-metal catalysis -- 5.1 Trends in aqueous transition-metal catalysis -- 5.2 Palladium-catalyzed cross-coupling reactions -- 5.3 Heck reaction -- 5.4 Carbonylation -- 5.5 Hydroformylation -- 5.6 Hydrogenation -- 5.7 Other reactions -- References -- 6 Oxidations and reductions in water -- 6.1 Oxidations in water: introduction -- 6.2 Oxidation of carbon-hydrogen bonds -- 6.3 Oxidation of carbon-carbon double bonds -- 6.4 Other oxidations -- 6.5 Reductions in water: introduction -- 6.6 Reduction of carbon-carbon double and triple bonds -- 6.7 Reduction of carbonyl and nitro functionalities -- 6.8 Other reductions -- References -- 7 Base-catalyzed aldol- and Michael-type condensations in aqueous media -- 7.1 Introduction -- 7.2 Claisen-Schmidt reaction -- 7.3 Vinylogous aldol reaction -- 7.4 Knoevenagel reaction -- 7.5 Tollens reaction -- 7.6 Weiss-Cook reaction -- 7.7 Michael reaction -- References -- 8 Water-stable rare-earth Lewis-add catalysis in aqueous and organic solvents -- 8.1 Introduction -- 8.2 Aldol reactions -- 8.3 Allylation reactions -- 8.4 Diels-Alder reactions -- 8.5 Mannich-type reactions -- 8.6 Imino Diels-Alder reactions: synthesis of pyridine and quinoline derivatives -- 8.7 Asymmetric aza Diels-Alder reactions: synthesis of tetrahydroquinoline derivatives using a chiral lanthanide Lewis acid as catalyst -- 8.8 Micellar systems -- Acknowledgements -- References.
In:
Springer Nature eBook
Weitere Ausg.:
Printed edition: ISBN 9789401060776
Weitere Ausg.:
Printed edition: ISBN 9789401149518
Weitere Ausg.:
Printed edition: ISBN 9780751404104
Sprache:
Englisch
DOI:
10.1007/978-94-011-4950-1
URL:
https://doi.org/10.1007/978-94-011-4950-1
