UID:
edoccha_9959733902302883
Format:
1 online resource (681 p.)
ISBN:
1-4832-9089-1
Series Statement:
Studies in Inorganic Chemistry ; 19
Content:
Molybdenum is an element with an extremely rich and interesting chemistry having very versatile applications in various fields of human activity. It is used extensively in metallurgical applications. Because of their anti-wear properties, molybdenum compounds find wide applications as lubricants - particularly in extreme or hostile environmental situations. Many molybdates and heteropolymolybdates are white and therefore used as pigments. In addition, they are non-toxic and act as efficient corrosion inhibitors and smoke suppressants. Hydroprocessing of petroleum is one of the largest industri
Note:
Description based upon print version of record.
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Front Cover; Molybdenum: An Outline of its Chemistry and Uses; Copyright Page; PREFACE; LIST OF CONTRIBUTORS; Table of Contents; Chapter 1. OCCURRENCE, EXTRACTION, PRODUCTION AND USES OF MOLYBDENUM; 1. INTRODUCTION; 2. GEOLOGICAL ORIGIN; 3. GEOCHEMISTRY OF PORPHYRIES; 4. DISTRIBUTION; 5. MINING; 6. BENEFICATION; 7. TECHNICAL GRADE MoO3; 8. PURE MoO3 AND MOLYBDATES; 9. WET CHEMICAL PROCESS; 10. MOLYBDENUM DISULPHIDE; 11. MOLYBDENUM METAL; 12. PRODUCTION OF Mo METAL; 13. CHEMICAL AND PHYSICAL PROPERTIES OF Mo; 14. MOLYBDEUM HEXACARBONYL [Mo(CO)6]
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15. THE INDUSTRIAL USES OF Mo AND ITS BASIC COMPOUNDS16. LUBRICATION (SOLID); 17. OIL SOLUBLE Mo COMPOUNDS (E.P. LUBRICANTS); 18. INCORPORATION IN PLASTICS; 19. BATTERIES; 20. CORROSION INHIBITION; 21. BASIC DYE COMPLEX PIGMENTS; 22. PIGMENTS AND INKS (ref. 185); 23. FIRE RETARDANCE AND SMOKE SUPPRESSION OF PLASTICS; 24. APPLICATIONS OF Mo METAL; 25. MOLYBDENUM METAL AND ITS ALLOYS; 26. THE BINARY ALLOYS; 27. Mo (SOLUTE) ALLOYING METAL IN STEELS; 28. INTERSTITIAL COMPOUNDS; 29. MOLYBDENUM CARBIDE; 30. MOLYBDENUM NITRIDES; 31. MOLYBDENUM BORIDES; 32. MOLYBDENUM SILICIDES
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33. AGRICULTURE AND HORTICULTUREREFERENCES; Chapter 2. AN INTRODUCTION TO THE CHEMISTRY OF MOLYBDENUM; 2.1 INTRODUCTION; 2.2 PROPERTIES OF THE ELEMENT; 2.3 CLASSIFICATION OF MOLYBDENUM COMPOUNDS; 2.4 THE CONSTRUCTION OF E.N. VERSUS V.N. PLOTS (CALLED MLX PLOTS); 2.5 DISCUSSION OF INDIVIDUAL MLX CLASSES OF MOLYBDENUM COMPOUNDS; 2.6 A DISCUSSION OF THE CHEMISTRY OF MOLYBDENUM IN VARIOUS LIGAND ENVIRONMENTS; 2.7 COMPARISON OF GENERALTRENDS IN THE CHEMISTRIES OF CHROMIUM, MOLYBDENUM AND TUNGSTEN; 2.8 CONCLUSION; APPENDIX TO CHAPTER; Chapter 3. THE OXIDE CHEMISTRY OF MOLYBDENUM; 3.1 INTRODUCTION
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3.2 BINARY OXIDES3.3 MOLYBDENUM OXIDE HYDRATES; 3.4 TERNARY OXIDES OF MOLYBDENUM; 3.5 SUGGESTIONS FOR FURTHER READING; 3.6 REFERENCES; CHAPTER 4. MOLYBDENUM SULPHUR CHEMISTRY; 1. INTRODUCTION; 2. THIOETHER CHEMISTRY; 3. DITHIOLENE CHEMISTRY; 4. 1,1-DITHIOLATE COMPLEXES; 5. THIOLATO-COMPLEXES; 6. MOLYBDENUM SULPHIDO- AND DISULPHIDO-COMPLEXES; 7. MOLYBDENUM SULPHIDES; 8. APPLICATIONS OF MOLYBDENUM SULPHUR COMPLEXES; 9. POSTSCRIPT; REFERENCES; Chapter 5. THE HALIDES OF MOLYBDENUM; 1. INTRODUCTION; 2. MOLYBDENUM FLUORIDES; 3. MOLYBDENUM CHLORIDES; 4. MOLYBDENUM BROMIDES; 5. MOLYBDENUM IODIDES
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6. OXIDE HALIDES OF MOLYBDENUM7. OXIDE-IODIDES OF MOLYBDENUM; 8. SULPHIDE-HALIDES OF MOLYBDENUM; 9. SELENIDE-CHLORIDES OF MOLYBDENUM; REFERENCES; Chapter 6. THE ORGANOMETALLIC AND METAL-ORGANIC CHEMISTRY OF MOLYBDENUM; 1. INTRODUCTION; 2 MOLYBDENUM CARBONYL; 3 ISOCYANIDE COMPLEXES; 4 CARBENE, ALKYLIDENE, VINYLIDENE, CARBYNE AND ALKYLIDYNE COMPLEXES; 5 COMPOUNDS CONTAINING MOLYBDENUM-CARBON σ BONDS; 6 ALKENE, POLYENE AND SIMPLE ALKYNE COMPLEXES; 7 ALLYL COMPLEXES; 8 CYCLOPROPENYL, CYCLOBUTADIENE AND TRMETHYLENEMETHANE COMPLEXES; 9 CYCLOPENTADIENYL COMPLEXES; 10 ARENE AND RELATED COMPLEXES
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11 NITROSYL COMPLEXES
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English
Additional Edition:
ISBN 1-322-26875-4
Additional Edition:
ISBN 0-444-88198-0
Language:
English
