UID:
edocfu_9958072776402883
Umfang:
1 online resource (1241 p.)
Ausgabe:
1st ed.
ISBN:
0-12-801082-7
Inhalt:
There are no shortcuts in organic chemistry. Understanding and mastery cannot be achieved without devoting adequate time and attention to the theories and concepts of the discipline. It is with this premise that Ouellette and Rawn set out to comprehensively survey the field in Organic Chemistry, with an emphasis on connecting the basic principles of organic chemistry to real world challenges that require analysis, not just recall. Organic chemistry is at the interface of physical and biological science, and this new text lays out the basic principles of organic chemistry in their relation to a host of other fields in both physical and biological sciences. Chemical bonding determines molecular structure, which in turn dictates physical, chemical, and biological properties from the smallest molecules to the largest. Molecular structure determines reaction mechanisms, from the smallest to the largest molecules. Reaction mechanisms determine strategies for organic synthesis, and these synthetic principles extend to every aspect of synthesis, from drug design to the methods cells employ to synthesize the molecules of which they are made. These relationships form a continuous narrative throughout the book, wherein principles logically evolve from one to the next, from the simplest to the most complex examples, with abundant connections between the text and real world applications. Contains extensive examples of biological relevance Includes an important chapter on organometallic chemistry not found in other standard references Extended, illustrated glossary Appendices on thermodynamics, kinetics, and transition state theory.
Anmerkung:
Includes index.
,
Front Cover; Organic Chemistry:Structure, Mechanism, and Synthesis; Copyright; Dedication; Contents; Acknowledgments; Preface; Chapter 1: Structure and Bonding in Organic Compounds; 1.1 Brief Review of Atomic Structure; 1.2 Atomic Properties; 1.3 Ionic and Covalent Bonds; 1.4 Strategies for Writing Lewis Structures; 1.5 Formal Charge; 1.6 Molecular Geometry; 1.7 Resonance Structures; 1.8 Valence Shell Electron Pair Repulsion Theory; 1.9 Dipole Moments; 1.10 Molecular Orbital Theory; 1.11 The Hydrogen Molecule; 1.12 Bonding in Carbon Compounds; 1.13 SP3 Hybridization of Carbon in Methane
,
1.14 SP3 Hybridization of Carbon in Ethane1.15 SP2 Hybridization of Carbon in Ethene; 1.16 SP Hybridization of Carbon in Ethyne; 1.17 Effect of Hybridization on Bond Length and Bond Strength; 1.18 Hybridization of Nitrogen; 1.19 Hybridization of Oxygen; Exercises; Chapter 2 : Part I: Functional Groups and Their Properties; 2.1 Introduction to Functional Groups: Hydrocarbons and Haloalkanes; 2.2 Functional Groups that Contain Oxygen; 2.3 Functional Groups that Contain Nitrogen; 2.4 Functional Groups that Contain Sulfur; 2.5 Structural Formulas; 2.6 Bond-Line Structures; 2.7 Isomers
,
Part II: Identification of Functional Groups by Infrared Spectroscopy2.8 Spectroscopy; 2.9 Infrared Spectroscopy; 2.10 Identifying Hydrocarbons; 2.11 Identifying Oxygen-Containing Compounds; 2.12 Identifying Nitrogen-Containing Compounds; 2.13 Bending Deformations; End-of-Chapter Exercises; Chapter 3: Introduction to Organic Reaction Mechanisms; 3.1 Acid-Base Reactions; 3.2 Chemical Equilibrium and Equilibrium Constants; 3.3 PH and PK Values; 3.4 Effect of Structure on Acidity; 3.5 Standard Free Energy Changes in Chemical Reactions; 3.6 Enthalpy Changes in Chemical Reactions
,
3.7 Bond Dissociation Energies3.8 Introduction to Reaction Mechanisms; 3.9 Structures and Stabilities of Carbon Radicals, Carbocations, and Carbanions; 3.10 Factors that Influence Reaction Rates; 3.11 Reaction Rate Theory; 3.12 Stability and Reactivity; End-of-Chapter Exercises; Chapter 4: Alkanes and Cycloalkanes: Structures and Reactions; 4.1 Classes of Hydrocarbons; 4.2 Alkanes; 4.3 Nomenclature of Alkanes; 4.4 Conformations of Alkanes; 4.5 Cycloalkanes; 4.6 Conformations of Cycloalkanes; 4.7 Conformational Mobility of Cyclohexane; 4.8 Monosubstituted Cyclohexanes
,
4.9 Disubstituted Cyclohexanes4.10 Polycyclic Molecules; 4.11 Physical Properties of Alkanes; 4.12 Stabilities of Alkyl Radicals; 4.13 Chlorination of an Alkane-A Radical Reaction; Exercises; Chapter 5: Alkenes Structures and Properties; 5.1 Alkenes; 5.2 Structure and Bonding of Alkenes; 5.3 Unsaturation Number; 5.4 Geometric Isomerism; 5.5 E,Z Nomenclature of Geometrical Isomers; 5.6 Nomenclature of Alkenes; 5.7 Physical Properties of Alkenes; 5.8 Stability of Alkenes; 5.9 Reduction of Alkenes; 5.10 Mechanism of Catalytic Hydrogenation; 5.11 Heats of Hydrogenation of Alkenes; Exercises
,
Chapter 6: Alkenes: Addition Reactions
,
English
Weitere Ausg.:
ISBN 0-12-800780-X
Sprache:
Englisch
