UID:
edocfu_9959777085302883
Format:
1 online resource (321 p.)
ISBN:
0-12-393221-1
,
978-0-08-092385-7
Content:
The Porphyrin Handbook
Note:
Description based upon print version of record.
,
Front Cover; The Porphyrin Handbook: Bioinorganic and Bioorganic Chemistry; Copyright Page; Table of Contents; Preface; Contributors to Volumes 1-20; Contents of Volumes 1-20; Chapter 62. Functional and Structural Analogs of the Dioxygen Reduction Site in Terminal Oxidases; I. Introduction: Heme/Cu Terminal Oxidases; II. Structural and Spectroscopic Models of the Heme a3/CuB Site; III. Reactivity of Heme a3/CuB Analogs Toward O2 Under Noncatalytic and Single Turnover; IV. Functional Analogs of the Dioxygen Reduction Site in Heme/Cu Terminal Oxidases; V. Cofacial Diporphyrins
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VI. Summary and OutlookReferences; Chapter 63. Heme Protein Dynamics: Electron Tunneling and Redox Triggered Foldin; I. Introduction; II. Semiclassical Theory of Electron Transfer; III. Reorganization Energies of Ru-Modified Heme Proteins; IV. Electronic Coupling; V. Tunneling Timetables; VI. Tunneling Across Heme Protein-Protein Interfaces; VII. Redox-Coupled Folding of Proteins; References; Chapter 64. Chiral Metalloporphyrins and Their Use in Enantiocontrol; I. Introduction; II. Syntheses of Chiral Porphyrins and Metalloporphyrins; III. Enantiocontrol with Chiral Metalloporphyrins
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IV. Transition Metal ChiroporphyrinsV. Perspectives; References; Chapter 65. Carbene Complexes of Metalloporphyrins and Heme Proteins; I. Introduction; II. Structure and Bonding; III. Methods of Synthesis of Metal-Carbene Bond in Porphyrins; IV. Synthetic Metal-Carbene Porphyrin Derivatives and Their Reactivity; V. Metalloporphyrins as Catalysts for Carbene Transfer; VI. Carbenes as Ligands to Heme Proteins; References; Chapter 66. Metalloporphyrins in the Biomimetic Oxidation of Lignin and Lignin Model Compounds: Development of Alternative Delignification Strategies; I. Introduction
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II. LigninIII. Lignin Degradation Enzymes Containing Porphyrins Prosthetic Group; IV. Models of Lignin Degradation Enzymes; V. Metalloporphyrins as Biomimetic Systems for Lignin and Lignin Model Compounds Degradation; VI. Conclusions; References; Chapter 67. Biochemistry of Methyl-CoM Reductase and Coenzyme F430; I. Introduction; II. Isolation and Activation of MCR; III. Structure of F4 30 and MCR; IV. Spectroscopic Studies of MCR; V. Mechanism of Methane Formation by MCR; VI. Summary and Perspectives for the Future; References
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Chapter 68. Structure, Reactions, and Functions of B1 2 and B12-ProteinsI. Introduction; II. B12: Structure and Reactivity; III. B12-Electrochemistry; IV. Reactivity of B12-Derivatives in Organometallic Reactions; V. B12-Cofactors in Enzymatic Reactions; VI. B12: Medical Aspects; References; Index
Language:
English
Keywords:
Electronic books.
