Kooperativer Bibliotheksverbund

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Format: 1 online resource (526 pages).

Edition: Fourth edition.

ISBN: 0-12-813293-0

Series Statement: Plastics Design Library

Note: Includes index. , Front Cover -- FILM PROPERTIES OF PLASTICS AND ELASTOMERS -- Series Page -- FILM PROPERTIES OF PLASTICS AND ELASTOMERS -- Copyright -- Contents -- Preface -- 1 - Introduction to Plastics and Polymers -- 1.1 Polymerization -- 1.1.1 Addition Polymerization -- 1.1.2 Condensation Polymerization -- 1.2 Copolymers -- 1.3 Linear, Branched, and Cross-linked Polymers -- 1.4 Polarity -- 1.5 Unsaturation -- 1.6 Steric Hindrance -- 1.7 Isomers -- 1.7.1 Structural Isomers -- 1.7.2 Geometric Isomers -- 1.7.3 Stereoisomers-Syndiotactic, Isotactic, Atactic -- 1.8 Inter- and Intramolecular Attractions in Polymers -- 1.8.1 Hydrogen Bonding -- 1.8.2 Van der Waals Forces -- 1.8.3 Chain Entanglement -- 1.9 General Classifications -- 1.9.1 Molecular Weight -- 1.9.2 Thermosets Versus Thermoplastics -- 1.9.3 Crystalline Versus Amorphous -- 1.9.4 Orientation -- 1.10 Plastic Compositions -- 1.10.1 Polymer Blends -- 1.10.2 Elastomers -- 1.10.3 Additives -- 1.10.3.1 Fillers, Reinforcement, Composites -- 1.10.3.2 Combustion Modifiers, Fire, Flame Retardants, and Smoke Suppressants -- 1.10.3.3 Release Agents -- 1.10.3.4 Slip Additives/Internal Lubricants -- 1.10.3.5 Antiblock Additives -- 1.10.3.6 Catalysts -- 1.10.3.7 Impact Modifiers and Tougheners -- 1.10.3.8 UV Stabilizers -- 1.10.3.9 Optical Brighteners -- 1.10.3.10 Plasticizers -- 1.10.3.11 Pigments, Extenders, Dyes, Mica -- 1.10.3.11.1 Titanium Dioxide -- 1.10.3.11.2 Carbon Black -- 1.10.3.12 Coupling Agents -- 1.10.3.13 Thermal Stabilizers -- 1.10.3.14 Antistatic and Conductivity -- 1.10.3.15 Antioxidants -- 1.10.3.16 Antifog Additives -- 1.10.3.17 Nucleating Agents/Clarifying Agents -- 1.10.3.18 Antimicrobials/Biocides -- 1.10.3.19 Oxygen Scavangers -- 1.10.3.20 Odor Absorbers -- 1.10.3.21 Desiccants -- 1.11 Polymer Nomenclature -- 1.12 Summary. , 2 - Introduction to the Mechanical, Thermal, and Permeation Properties of Plastics and Elastomer Films -- 2.1 Physical Property Testing of Plastic Films -- 2.1.1 Specific Gravity and Density -- 2.1.2 Dimensional Stability on Heating -- 2.1.3 Hygroscopic Expansion -- 2.1.4 Residual Shrinkage/Strain Relief -- 2.1.5 Coefficient of Thermal Expansion -- 2.1.6 Appearance: Color, Haze, and Gloss -- 2.1.6.1 Color -- 2.1.6.2 Gloss Measurement -- 2.1.6.3 Haze Measurement -- 2.1.7 Coefficient of Friction -- 2.2 Mechanical Testing of Plastic Films -- 2.2.1 Tensile Properties -- 2.2.2 Flexural Properties -- 2.2.3 Folding Endurance (MIT Flex Life Machine) -- 2.2.4 Puncture Properties -- 2.2.4.1 High-Speed Puncture Test -- 2.2.4.2 Drop Dart Impact Test for Plastics Film -- 2.2.4.3 Spencer Impact Test -- 2.2.5 Tear Properties -- 2.2.5.1 Elmendorf Tear Strength -- 2.2.5.2 Trouser Tear Resistance -- 2.3 Thermal Property Testing of Plastic Films -- 2.3.1 Melt Flow Index -- 2.3.2 Melting Point, Tm -- 2.3.3 Glass Transition Temperature, Tg -- 2.3.4 Other Thermal Tests -- 2.4 Electrical Properties of Films -- 2.4.1 Dielectric Constant (or Relative Permittivity) -- 2.4.2 Dissipation Factor -- 2.4.3 Dielectric Strength -- 2.4.4 Surface Resistivity -- 2.4.5 Volume Resistivity -- 2.5 Permeation of Films -- 2.5.1 History -- 2.5.2 Transport of Gases and Vapors Though Solid Materials -- 2.5.3 Effusion -- 2.5.4 Solution-Diffusion and Pore-Flow Models -- 2.5.4.1 Non-Fickian Diffusion -- 2.5.4.2 Dependence of Permeability, Diffusion, and Solubility Pressure -- 2.5.4.3 Dependence of Permeability, Diffusion, and Solubility on Temperature-The Arrhenius Equation -- 2.5.5 Multiple-layered Films -- 2.5.6 Permeation and Vapor Transmission Testing -- 2.5.6.1 Units of Measurement -- 2.5.6.2 Gas Permeation Test Cells -- 2.5.6.3 Vapor Permeation Cup Testing. , 2.5.6.4 Mass Spectrometry and Calibrated Standard Gas Leaks -- 2.5.6.5 Standard Tests for Permeation and Vapor Transmission -- 3 - Production of Films -- 3.1 Extrusion -- 3.2 Blown Film -- 3.3 Calendering -- 3.4 Casting Film Lines -- 3.5 Post-Film Formation Processing -- 3.6 Web Coating -- 3.6.1 Gravure Coating -- 3.6.2 Reverse Roll Coating -- 3.6.3 Knife on Roll Coating -- 3.6.4 Metering Rod (Meyer Rod) Coating -- 3.6.5 Slot Die (Slot, Extrusion) Coating -- 3.6.6 Immersion (Dip) Coating -- 3.6.7 Vacuum Deposition -- 3.6.8 Web Coating Process Summary -- 3.7 Lamination -- 3.7.1 Hot Roll/Belt Lamination -- 3.7.2 Flame Lamination -- 3.8 Orientation -- 3.8.1 Machine Direction Orientation -- 3.8.2 Biaxial Orientation -- 3.8.3 Blown Film Orientation -- 3.9 Skiving -- 3.10 Coatings -- 3.11 Summary -- 4 - Uses of Barrier Films -- 4.1 Barrier Films in Packaging -- 4.1.1 Water Vapor -- 4.1.2 Atmospheric Gases -- 4.1.3 Odors and Flavors -- 4.2 Markets and Applications of Barrier Films -- 4.3 EVAL™ Ethylene Vinyl Alcohol Copolymer-Based Multiple Layered Films and Their Applications -- 4.4 Some Illustrated Applications of Multiple Layered Films -- 5 - Styrenic Plastics -- 5.1 Acrylonitrile-Butadiene-Styrene Copolymer -- 5.2 Acrylonitrile-Styrene-Acrylate -- 5.3 Polystyrene -- 5.4 Styrene-Acrylonitrile Copolymer -- 5.5 Styrenic Block Copolymers -- 6 - Polyesters -- 6.1 Polycarbonate -- 6.2 Polybutylene Terephthalate -- 6.3 Polyethylene Terephthalate -- 6.3.1 DuPont™ Teijin Films™ -- 6.3.2 Mitsubishi Polyester Film Hostaphan® -- 6.3.3 Toray Industries Lumirror® -- 6.3.4 Generic -- 6.4 Liquid Crystalline Polymers -- 6.5 Polycyclohexylene-Dimethylene Terephthalate -- 6.6 Polyethylene Naphthalate -- 6.7 Copolyesters -- 7 - Polyimides -- 7.1 Polyamide-Imide -- 7.2 Polyetherimide -- 7.3 Polyimide -- 7.3.1 DuPont™ Kapton® -- 7.3.2 UBE Industries Upilex® Polyimide Films. , 7.3.3 Saint-Gobain Norton -- 7.4 Thermoplastic Polyimide -- 8 - Polyamides (Nylons) -- 8.1 Polyamide 6 (Nylon 6) -- 8.1.1 Honeywell -- 8.1.2 EMS Grivory -- 8.1.3 UBE -- 8.1.4 Generic Nylon 6 -- 8.2 Polyamide 11 (Nylon 11) -- 8.3 Polyamide 12 (Nylon 12) -- 8.4 Polyamide 66 (Nylon 66) -- 8.5 Polyamide 610 (Nylon 610) -- 8.6 Polyamide 66/610 (Nylon 66/610) -- 8.7 Polyamide 6/12 (Nylon 6/12) -- 8.8 Polyamide 666 (Nylon 666 or 6/66) -- 8.9 Polyamide 6/69 (Nylon 6/6.9) -- 8.10 Polyamide 1010 (Nylon 1010) -- 8.11 Polyamide 1012 (Nylon 1012) -- 8.12 Amorphous Polyamides -- 8.13 Nylon PACM-12 -- 8.14 Polyarylamide -- 9 - Polyolefins -- 9.1 Polyethylene -- 9.1.1 Unclassified Polyethylene -- 9.1.2 Ultralow-Density Polyethylene -- 9.1.3 Linear Low-Density Polyethylene -- 9.1.4 Low-Density Polyethylene -- 9.1.5 Medium-Density Polyethylene -- 9.1.6 High-Density Polyethylene -- 9.1.6.1 LyondellBasell -- 9.1.6.2 Equistar Chemicals -- 9.1.6.3 ExxonMobil™ -- 9.1.6.4 NOVA Chemicals High-Density Polyethylene -- 9.1.7 Metallocene Polyethylene -- 9.1.8 Enhanced Polyethylene -- 9.2 Polypropylene -- 9.3 Polybutadiene -- 9.4 Polymethyl Pentene -- 9.5 Cyclic Olefin Copolymer -- 9.6 Plastomer -- 10 - Polyvinyls and Acrylics -- 10.1 Ethylene-Vinyl Acetate Copolymer -- 10.1.1 DuPont™ Elvax® -- 10.1.2 Arkema Evatane® -- 10.1.3 LyondellBasell Ultrathene Ethylene-Vinyl Acetate Copolymers -- 10.2 Ethylene-Vinyl Alcohol Copolymer -- 10.2.1 Kuraray EVAL™ -- 10.2.2 Nippon Gohsei Soarnol® -- 10.3 Polyvinyl Alcohol -- 10.4 Polyvinyl Chloride -- 10.5 Polyvinylidene Chloride -- 10.6 Polyacrylics -- 10.7 Acrylonitrile-Methyl Acrylate Copolymer -- 10.8 Ionomers -- 10.8.1 DuPont™ Surlyn® -- 10.8.2 ExxonMobil Chemical Iotek™ Ionomer Films -- 11 - Fluoropolymers -- 11.1 Polytetrafluoroethylene -- 11.2 Fluorinated Ethylene Propylene -- 11.2.1 Chemours Teflon® Fluorinated Ethylene Propylene. , 11.2.2 Daikin Neoflon™ Fluorinated Ethylene Propylene -- 11.2.3 Generic/Unspecified Fluorinated Ethylene Propylene -- 11.3 Perfluoroalkoxy -- 11.3.1 PFA -- 11.3.2 Perfluoromethoxy -- 11.4 Hexafluoropropylene, Tetrafluoroethylene, Ethylene Terpolymer -- 11.5 Tetrafluoroethylene, Hexafluoropropylene, Vinylidene Fluoride Terpolymer™ -- 11.6 Amorphous Fluoropolymer-Teflon AF® -- 11.7 Polyvinyl Fluoride -- 11.7.1 DuPont Tedlar® -- 11.8 Polychlorotrifluoroethylene -- 11.8.1 Honeywell Aclar® PCTFE Film -- 11.8.2 Daikin Industries Neoflon® PCTFE Film -- 11.8.3 Arkema Voltalef® PCTFE Film -- 11.9 Polyvinylidene Fluoride -- 11.10 Ethylene-Tetrafluoroethylene Copolymer -- 11.10.1 Chemours Tefzel® -- 11.10.2 Saint-Gobain Performance Plastics Norton® ETFE -- 11.10.3 Asahi Glass Fluon® -- 11.10.4 Generic Ethylene-Tetrafluoroethylene Copolymer -- 11.11 Ethylene-Chlorotrifluoroethylene Copolymer -- 11.12 Summary -- 12 - High-Temperature/High-Performance Polymers -- 12.1 Polyaryletherketones -- 12.2 Polyphenylene Sulfide -- 12.3 Polysulfone -- 12.4 Polyethersulfone -- 12.5 Polybenzimidazole -- 12.6 Parylene (Poly(p-Xylylene)) -- 12.7 Polyphenylene Sulfone -- 13 - Elastomers and Rubbers -- 13.1 Thermoplastic Polyurethane Elastomers -- 13.2 Olefinic Thermoplastic Elastomers -- 13.3 Thermoplastic Copolyester Elastomers -- 13.4 Thermoplastic Polyether Block Polyamide Elastomers -- 13.5 Styrenic Butadiene Copolymer Thermoplastic Elastomers -- 13.6 Syndiotactic 1,2-Polybutadiene -- 13.7 Polysiloxane -- 14 - Renewable Resource and Biodegradable Polymers -- 14.1 Cellophane™ -- 14.2 Nitrocellulose -- 14.3 Cellulose Acetate -- 14.4 Cellulose Acetate Butyrate -- 14.5 Cellulose Acetate Propionate -- 14.6 Ethyl Cellulose -- 14.7 Polycaprolactone -- 14.8 Poly(Lactic Acid) -- 14.9 Poly-3-Hydroxybutyrate -- 14.10 Polyglycolic Acid -- 15 - Multilayered Films. , 15.1 Prediction of Properties of Multilayered Films.

Additional Edition: ISBN 0-12-813292-2

Language: English