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Umfang: 1 online resource (431 pages)

ISBN: 9780128221266 , 0128221267

Serie: Developments in Inorganic Chemistry ; v.Volume 2

Inhalt: Fundamentals and Applications of Boron Chemistry highlights its impressive potential for current and future developments across a range of fields, providing foundational information on boron chemistry and systematically summarizing applications of boron in energy, medicinal chemistry, and materials chemistry.

Anmerkung: Front Cover -- Fundamentals and Applications of Boron Chemistry -- Copyright Page -- Contents -- List of contributors -- Preface -- 1 Introduction: basic concept of boron and its physical and chemical properties -- 1.1 Boron element and its isotopes -- 1.2 General bonding characteristics and crystal structure -- 1.2.1 Bonding characteristics -- 1.2.2 Crystal structure -- 1.3 General physical and chemical properties -- 1.3.1 Physical properties -- 1.3.2 Chemical properties -- 1.4 The history, distribution, and sources of boron -- 1.4.1 The history of boron -- 1.4.2 Natural distribution and source of boron -- 1.4.2.1 Natural distribution -- 1.4.2.2 Naturally occurring form -- 1.4.3 Other sources of boron -- 1.5 Determination of boron isotopes -- 1.5.1 Extraction of boron -- 1.5.1.1 Alkali fusion method -- 1.5.1.2 Acid decomposition method -- 1.5.1.3 High temperature hydrolysis method -- 1.5.2 Separation and purification of boron -- 1.5.2.1 Methyl borate distillation method -- 1.5.2.2 Ion-exchange method -- 1.5.2.3 Evaporative concentration of boron solution -- 1.5.3 The determination of isotope mass spectrometry -- 1.5.3.1 Positive thermal ionization mass spectrometry -- 1.5.3.1.1 Na2BO2+ Ion mass spectrometry -- 1.5.3.1.2 Cs2BO2+ Ion mass spectrometry and graphite coating technology -- 1.5.3.2 Negative thermal ionization mass spectrometry -- 1.5.3.3 Mass peak superimposed interference -- 1.5.3.4 Mass divergence effect -- 1.6 The pharmacokinetics of boron -- 1.6.1 Absorption and transport of boron -- 1.6.2 Daily intake of boron with the diet -- 1.6.3 Toxic effects of boron -- 1.7 The preparation of boron -- 1.7.1 Halide hydrogen reduction method -- 1.7.2 Metal thermal reduction method -- 1.7.3 Molten salt electrolysis method -- 1.7.4 Thermal decomposition method -- 1.7.5 Short summary. , 1.8 Special chemical compounds of boron and their applications -- 1.8.1 Borane -- 1.8.1.1 Trihydridoboron -- 1.8.1.2 Diborane -- 1.8.2 Carboranes -- 1.8.3 Carborane acids -- 1.8.4 Borene -- 1.8.5 Boron carbide -- 1.8.6 Boron nitrides and boron nitride nanotubes -- 1.8.7 Boron oxide -- 1.8.8 Magnesium diboride -- 1.8.9 Calcium hexaboride -- 1.8.10 Rhenium diboride -- 1.9 Boron in plants, human and animal health -- 1.9.1 Boron in plants -- 1.9.2 Boron requirement of microorganisms -- 1.9.3 Boron in human and animal health -- 1.10 Medical applications -- 1.10.1 Natural boron compounds -- 1.10.2 Boron containing drugs approved by FDA -- 1.10.3 Boron neutron capture therapy -- 1.11 Summary and outlook -- Acknowledgments -- References -- 2 Applications of boron compounds in catalysis -- 2.1 Introduction -- 2.2 Triaryl or mixed arylalkylboranes -- 2.3 Diaryl boranes or diaryl borinic acids -- 2.4 Arylboronic acid -- 2.5 Borocation -- 2.6 Miscellaneous -- 2.7 Conclusion -- References -- 3 Boron-containing small molecules as antiparasitic agents -- 3.1 Introduction -- 3.2 Therapeutic application -- 3.2.1 Tuberculosis and antifungal activity -- 3.2.1.1 Benzoxaboroles -- 3.2.1.2 Peptidyl boronates/boronic acids -- 3.2.1.3 Others boron small compounds (diazoborines and antibiotic) -- 3.2.2 Malaria -- 3.2.3 Neglected tropical diseases -- 3.2.3.1 Trypanosomiasis -- 3.2.3.2 Leishmaniasis -- 3.2.3.3 Onchocerciasis (river blindness) and lymphatic filariasis (elephantiasis) -- 3.2.4 Cryptosporidiosis and toxoplasmosis -- 3.3 Conclusion -- Abbreviations -- References -- 4 Boron materials for energy applications -- 4.1 Introduction -- 4.2 Boron materials for hydrogen generation -- 4.2.1 Summary and outlook of boron-based hydrogen generation -- 4.3 Boron materials for organic light-emitting diodes -- 4.3.1 Summary and outlook of boron-based OLEDs. , 4.4 Boron materials thermal conductivity -- 4.4.1 Boron arsenide (BAs) for thermal conductivity -- 4.4.2 Boron nitride (BN) for thermal conductivity -- 4.4.3 Boron isotope effect on thermal conductivity -- 4.4.4 Influence of layer number of h-BN on thermal conductivity -- 4.4.5 Boron nitride nanocomposites for thermal conductivity -- 4.4.6 Phase change materials for thermal conductivity -- 4.4.6.1 Summary and outlook of boron materials thermal conductivity -- 4.5 Piezoelectric properties of boron-based materials -- 4.5.1 Piezoelectric properties of boron materials (theoretical study) -- 4.5.2 Piezoelectric properties of boron materials (experimental study) -- 4.5.2.1 Summary and outlook of piezoelectric properties of boron materials -- 4.6 Boron materials for energy storage -- 4.6.1 Boron materials for hydrogen storage -- 4.6.1.1 Borohydrides -- 4.6.1.2 Amine boranes -- 4.6.1.3 Octahydrotriborates -- 4.6.1.4 Boron-doped carbonaceous materials for hydrogen storage -- 4.6.1.5 h-BN for hydrogen storage -- 4.6.1.6 BCN Heterocyclic compounds for hydrogen storage -- 4.6.1.7 Boron materials for hydrogen storage (theoretical Study) -- 4.6.1.7.1 Summary and outlook for hydrogen storage -- 4.6.2 Boron materials for rechargeable batteries -- 4.6.2.1 Boron materials for Li-ion batteries -- 4.6.2.2 Boron materials for lithium-sulfur batteries -- 4.6.2.3 Boron materials for magnesium and sodium ion batteries -- 4.6.2.4 Boron materials for rechargeable batteries (theoretical study) -- 4.6.2.4.1 Summary and outlook of boron materials for rechargeable batteries -- 4.6.3 Boron materials for supercapacitor -- 4.6.3.1 Boron-doped carbon-based supercapcitors -- 4.6.3.2 Boron with different anode material for hybrid supercapacitors -- 4.6.3.3 h-BN based supercapacitors -- 4.6.3.4 Boron doped diamond based supercapacitors. , 4.6.3.4.1 Summary and outlook of boron-based supercapacitors -- 4.6.4 Boron materials in photovoltaic/solar cells -- 4.6.4.1 Boron-based materials for silicon solar cell -- 4.6.4.2 Boron-based materials for perovskite solar cells (PSCs) -- 4.6.4.3 Boron materials for dye-sensitized solar cells -- 4.6.4.4 Boron materials in photovoltaic/solar cells (theoretical study) -- 4.6.4.4.1 Summary and Outlook of boron materials in photovoltaic/solar cells -- 4.7 Summary and outlook of boron materials for energy applications -- References -- 5 Nanovehicles and boron clusters -- 5.1 Overview -- 5.2 Boron clusters -- 5.2.1 Boron-rich clusters -- 5.2.1.1 Boron-rich icosahedral clusters -- 5.2.1.2 Boron-rich clusters beyond icosahedron -- 5.2.1.3 Transition metal bis(dicarbollide) clusters: rotary molecular motors -- 5.2.2 Boron-based nanomaterials of zero-dimensional to two-dimensional -- 5.2.2.1 Zero-dimensional nanomaterials of boron -- 5.2.2.2 One-dimensional and two-dimensional nanomaterials of bulky boron -- 5.3 Nanovehicles incorporating boron clusters -- 5.3.1 Nanocars -- 5.3.2 Spiroborate -- 5.3.3 Molecular turnstiles -- 5.3.4 Dendrimers -- 5.3.5 Liposomes -- 5.4 Future perspectives -- Acknowledgments -- References -- 6 The serendipitous integration of small boron-embedded molecules into medicinal chemistry -- 6.1 Introduction -- 6.2 Boron: detrimental to plant and animal physiology! -- 6.2.1 Toxicology of boron-containing compounds -- 6.3 Relevance of boron-containing compounds integrated into medicinal chemistry -- 6.3.1 Overview of FDA-approved and prospective boron-containing compounds -- 6.3.2 The extent of small boron-containing molecules in medicinal chemistry: boric, boronic, and boronate-based compounds -- 6.3.3 Boric acid: structure, properties, and medicinal capacity -- 6.3.3.1 Production, structure, and physiochemical properties of boric acid. , 6.3.3.2 Medicinal capacity of boric acid -- 6.3.4 Boronic acids and derivatives: structure, properties, and medicinal capacity -- 6.3.4.1 Structure and physiochemical properties of boronic acids and their derivatives -- 6.3.4.2 Synthesis and critical reactions of boronic acids and their derivatives -- 6.3.4.2.1 Synthesis of boronic acids and their derivatives -- 6.3.4.2.2 Critical reactions of boronic acids and their derivatives -- 6.3.4.3 Medicinal capacity of boronic acids and their derivatives -- 6.3.4.3.1 Antitumor capacity: "warheads" and "prodrugs" -- 6.3.4.3.2 Antimicrobial "warhead" capacity: antibacterial and antiviral agents -- 6.3.4.3.3 Multidisciplinary capacity: bioconjugation, chemosensors, molecular recognition, self-healing hydrogels, and drug... -- 6.3.5 Contrasting small boron bearing organic compounds versus small boron-based inorganic clusters: structure, properties,... -- 6.3.5.1 Highlighting the medicinal capacity of closo-clusters in antitumor and antimicrobial therapy -- 6.4 Conclusion -- References -- Index -- Back Cover.

Weitere Ausg.: Print version: Zhu, Yinghuai Fundamentals and Applications of Boron Chemistry San Diego : Elsevier,c2022 ISBN 9780128221273

Sprache: Englisch