Umfang:
1 Online-Ressource (xxiii, 565 Seiten)
,
Illustrationen, Diagramme
ISBN:
9781788016483
Serie:
New developments in NMR 20
Inhalt:
Cover; Foreword; Preface; Editor Biographies; Contents; Section 1: Introduction; Chapter 1 Applications of NMR in Polymer Characterization -- An Introduction; 1.1 Polymers and NMR -- Variety of Materials, Properties, Phenomena and Methods; 1.2 1H NMR Relaxometry and Time-domain Methods for Polymer Characterization; Acknowledgements; References; Section 2: Dynamics and Interactions in Solutions or Liquids; Chapter 2 Application of STD NMR in Organic/Inorganic Polymer Materials; 2.1 STD NMR; 2.2 Applications of STD NMR in Organic Polymers; 2.3 Applications of STD NMR in Inorganic Materials
Inhalt:
2.4 Mechanism of STD in the TBP-TiO2 System2.5 Conclusion; References; Chapter 3 Diffusion and Relaxometry to Study Carbohydrates Dissolved in Ionic Liquids; 3.1 Introduction; 3.2 Experimental Methods; 3.2.1 NMR Diffusion; 3.2.2 NMR Relaxometry; 3.2.3 Viscosity; 3.2.4 Materials; 3.2.5 Sample Preparation; 3.3 Results and Discussion; 3.3.1 Xylose Results; 3.3.2 Xylan Results; 3.4 Conclusion; Acknowledgements; References; Chapter 4 High Resolution Magic Angle Spinning (HRMAS) Pulse Field Gradient (PFG) NMR Diffusometry Studies of Swollen Polymers; 4.1 Introduction; 4.2 Background and Methods
Inhalt:
4.2.1 HRMAS NMR4.2.2 HRMAS NMR Diffusometry; 4.2.3 Polymer Materials; 4.3 Results and Discussion; 4.3.1 Octane Diffusion in 3D-printed Siloxane; 4.3.2 Diffusion of Solvent Mixtures in Swollen PDMS; 4.3.3 Diffusion in Methanol Fuel Cell Membranes; 4.4 Conclusions; Acknowledgements; References; Chapter 5 Application of On-line SEC-NMR and DOSY for Practical Polymer Characterization; 5.1 Introduction; 5.2 Characterization of Ethylene-Propylene-Diene Terpolymer (EPDM) by SEC-NMR and DOSY; 5.3 Characterization of Acrylic Copolymers by SEC-NMRand DOSY with Cryogenically Cooled Probe Technology
Inhalt:
5.4 Characterization of High Molecular Weight Acrylic Copolymers by DOSY with High Field-gradients5.5 Conclusion; References; Chapter 6 Dynamics of Polymer Systems Studied by NMR Field-cycling Relaxometry; 6.1 Introduction; 6.2 Theoretical Background; 6.3 Results; 6.3.1 Dynamics in Polymer Melts; 6.3.2 Dendrimers; 6.4 Outlook; Acknowledgements; References; Section 3: High-resolution MAS NMR of Soft Samples; Chapter 7 HR-MAS NMR Characterization of Thermo-responsive Polymer Gels: Network Collapse Dynamics and Intermolecular Interactions; 7.1 Introduction; 7.2 Principle of HR-MAS NMR Methods
Inhalt:
7.3 HR-MAS NMR Characterization of Thermo-responsive Polymer Gels7.3.1 HR-MAS NMR Methods for Polymer Gels Characterization; 7.3.2 Network Collapse Dynamics of Polymer Gels; 7.3.3 Intermolecular Interactions between Polymers and Small Molecules; 7.4 Conclusion; Acknowledgements; References; Chapter 8 Rubber-state NMR Spectroscopy; 8.1 Introduction; 8.2 Rubber State; 8.3 Vulcanized Natural Rubber; 8.4 Vulcanized Chloroprene Rubber; 8.5 Conclusion; References; Section 4: Dynamically Heterogeneous Systems and Nanocomposites
Inhalt:
Focuses specifically on NMR investigation of complex polymers for the polymer community as well as NMR spectroscopists, and will push the development of both fields. It will cover the latest advances and show how these novel NMR methods characterize various synthetic and natural polymers
Weitere Ausg.:
ISBN 9781788014007
Weitere Ausg.:
Erscheint auch als Druck-Ausgabe NMR methods for characterization of synthetic and natural polymers Cambridge : Royal Society of Chemistry, 2019 ISBN 9781788014007
Sprache:
Englisch
Fachgebiete:
Chemie/Pharmazie
Schlagwort(e):
Makromolekulare Chemie
;
NMR-Spektroskopie
;
Aufsatzsammlung
DOI:
10.1039/9781788016483
