Format:
X, 206 Seiten
,
Illustrationen
,
23 cm
Edition:
First published
ISBN:
0-521-47387-X
,
0-521-47933-9
Note:
MAB0014.001: AWI A12-95-0117
,
Includes index
,
Contents
Preface
1 Chemical equilibrium
1.1 Some introductory concepts
1.2 Equilibrium constants
1.3 Reaction quotient
1.4 LeChatelier' s principle
Exercises
2 Chemical thermodynamics
2.1 The first law of thermodynamics; enthalpy
2.2 Enthalpies of reaction and formation
2.3 Entropy and the second law of thermodynamics
2.4 The third law of thermodynamics; absolute entropies
2.5 Criteria for equilibrium and spontaneous transformation
2.6 Standard free energy changes
2. 7 Free energy change and the equilibrium constant
2.8 Chemical potential; homogeneous nucleation of water-vapor condensation
Exercises
3 Chemical kinetics
3.1 Reaction rates
3.2 Reaction mechanisms
3.3 Reaction rates and equilibria
3.4 Collision theory of gaseous reactions
3.5 The effect of temperature on reaction rates: the Arrhenius' relation
3.6 Catalysis
3.7 Half-life, residence time, and renewal time
Exercises
4 Solution chemistry and aqueous equilibria
4.1 Definitions and types of solutions
4.2 Solution concentrations
4.3 Factors affecting solubility
4.4 Colligative properties
4.5 Aqueous solutions; electrolytes
4.6 Aqueous equilibria
4.7 Strong and weak electrolytes; ion-product constant for water
Exercises
5 Acids and bases
5.1 Some definitions and concepts
5.2 The nature of H+(aq)
5.3 The Brønsted-Lowry theory; conjugate acid-base pairs
5.4 The Lewis theory 8
5.5 Strengths of acids and bases; acid-dissociation (or ionization) constant
5.6 The pH scale
5.7 Polyprotic acids
5.8 Hydrolysis
5.9 Buffers
5.10 Complex ions
5.11 Mass balance and charge balance relations
5.12 The pH of rainwater
Exercises
6 Oxidation-reduction reactions
6.1 Some definitions
6.2 Oxidation numbers
6.3 Balancing oxidation-reduction reactions
6.4 Half-reactions in electrochemical cells
6.5 Strengths of oxidants and reductants; standard cell and half-cell potentials
6.6 Standard cell potentials and free-energy change
6.7 The Nernst equation
6.8 Redox potentials; Eh-pH diagrams
6.9 Gram-equivalent weight and normality
Exercises
7 Photochemistry
7.1 Some properties of electromagnetic waves
7.2 Some photochemical terminology and principles
7.3 Quantum yields
7.4 Rate coefficients for photolysis
7.5 Photostationary states
7.6 Stratospheric ozone and photochemistry; depletion of stratospheric ozone
Exercises
Appendix I International system of units (SI)
Appendix II Some useful numerical values
Appendix III Atomic weights
Appendix IV Equilibrium (or dissociation) constants for some chemical reactions
Appendix V Some molar standard Gibbs free energies of formation, molar standard enthalpies (or heats) of formation and molar absolute entropies at 25°C and 1 atmosphere
Appendix VI Names, formulas, and charges of some common ions
Appendix VII Answers to exercises and hints and solutions to selected exercises
Index
Language:
English
Keywords:
Lehrbuch
URL:
http://digitale-objekte.hbz-nrw.de/storage2/2018/06/10/file_9/7884781.pdf
