UID:
almahu_9948025382902882
Umfang:
1 online resource (777 p.)
Ausgabe:
1st ed.
ISBN:
1-281-03434-7
,
9786611034344
,
0-08-054021-X
Serie:
Studies in physical and theoretical chemistry ; 87
Inhalt:
During the twentieth century, radiation chemistry emerged as a multi-faceted field encompassing all areas of science. Radiation chemical techniques are becoming increasingly popular and are being routinely used not only by chemists but also by biologists, polymer scientists, etc. ""Radiation Chemistry: Present Status and Future Trends"" presents an overall view of the different aspects of the subject. The chapters review the current status of the field and present the future opportunities in utilizing radiation chemical techniques. This will be of interest to chemists in genera
Anmerkung:
Description based upon print version of record.
,
Front Cover; Radiation Chemistry: Present Status and Future Trends; Copyright Page; Table of Contents; Preface; List of Authors; Chapter 1. Radiation chemistry: from the early days to the next millennium; Introduction; Theory; Instrumentation; Homogeneous systems; Organized assemblies and heterogeneous systems; Applications; Conclusions; References; Chapter 2. Accelerators for ultrafast phenomena; Introduction; Acceleration methods for ultrafast studies; Beam transport and pulse compression techniques; Pulse width determination; Experimental detection methods; Conclusion; References
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Chapter 3. Ion-beam radiation chemistryIntroduction; Energy deposition processes; Experimental techniques; Water and aqueous solutions; Organic liquids; Polymeric systems; References; Chapter 4. Radiation chemistry under magnetic fields - Spin coherence effects; Introduction; Singlet-correlated radical ion pairs in irradiated alkanes; Stationary effects, mary-spectroscopy; Time-resolved effects, quantum beats; Conclusion; References; Chapter 5. Muonium chemistry; Introduction; The muon, an end-of-track probe; Muonium reactions and kinetic isotope effects
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Solvation and diffusion of water hydrogen isotopes in waterMuonium-Substituted Free Radicals; Potential and future prospects; References; Chapter 6. Fundamental processes in gas-phase radiation chemistry; Introduction; The physical stage; Physico-chemical stage; Electron thermalization; The chemical stage; Detection techniques; Ion-ion recombination; Xe2+/SF6 ionic recombination; Xe2+/Br- ionic recombination; Absolute excitation and emission yields; Applications of gas phase radiation chemistry; References; Chapter 7. High temperature water radiolysis; Introduction
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Scheme for the radiolysis of waterMeasurement of g-values; Measurement of rate constants of spur reactions; Modelling of spur and track processes up to 300°C; Non-linear arrhenius behaviour of rate constants; Concluding remarks; References; Chapter 8. Radiation chemistry of concentrated inorganic aqueous solutions; Direct & indirect action of radiation in aqueous solutions; Nitric acid and nitrate solutions; Sulfuric acid and sulfate solutions; Phosphoric acid and phosphate solutions; Perchloric acid and perchlorate solutions; Other solutions; References
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Chapter 9. Radiation chemistry of organic liquids: saturated hydrocarbonsIntroduction; Solvent holes with anomalously high mobility; Single-pair and multiple-pair spurs; Generation of solvent and solute excited states; Concluding remarks; References; Chapter 10. Radiation chemistry of organic halides in aqueous solutions; Introduction; Formation of transient species; Oxidation potential of solute radical cations; Conclusions; References; Chapter 11. Radiation chemistry of fullerenes; Introduction; [60], [70], [76], [78] and [84]fullerenes; Monofunctionalized fullerene derivatives
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Multiply functionalized fullerene derivatives
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English
Weitere Ausg.:
ISBN 0-444-82902-4
Sprache:
Englisch
