UID:
almahu_9948026787002882
Umfang:
1 online resource (363 p.)
ISBN:
1-281-02340-X
,
9786611023409
,
0-08-052480-X
Inhalt:
The features of this book which will be of special interest to academic organic chemists are the introduction (Chapter 1), which presents a short course on the concepts and language of heterogeneous catalysis, covers organic reaction mechanisms of hydrogenation (Chapter 2), hydrogenolysis (Chapter 4), and oxidation (Chapter 6), a presents problems and solutions specific for running heterogeneous catalytic organic reactions in solution. These materials can supplement advanced chemistry courses.Most synthetic organic chemists use a variety of ""protecting groups"" which they attach to f
Anmerkung:
Description based upon print version of record.
,
Front Cover; Heterogeneous Catalysis in Organic Chemistry; Contents; Preface; Chapter 1. Introduction to Catalysis; 1.1. Definitions and Language of Catalysis; 1.2. Special Considerations for Heterogeneous Catalysis in Liquids; 1.3. Drawing and Naming Surface Species in Organic Reactions on Surfaces; 1.4. Hydrogen Sources; 1.5. Books on Heterogeneous Catalysis of Organic Reactions; References; Chapter 2. Hydrogenations; 2.1. Hydrogenation of Carbon-Carbon Multiple Bonds; 2.2. Hydrogenation of C=O Bonds; 2.3. Hydrogenation of Nitrogen-Containing Multiple Bonds and Reductive Amination
,
2.4. Hydrogen SourcesReferences; Chapter 3. Enantioselective Hydrogenations; 3.1. Basic Concepts; 3.2. Considerations of Chiral Surfaces; 3.3. Mechanisms of Enantioselectivity on Surfaces; References; Chapter 4. Hydrogenolysis; 4.1. Breaking C-O Bonds; 4.2. Breaking C-N Bonds; 4.3. Hydrogenolysis of C-S Bonds; 4.4. Hydrogenolysis of C-Se Bonds; 4.5. Hydrogenolysis of C-Halogen Bonds; 4.6. Hydrogenolysis of C-Si Bonds; 4.7. Hydrogenolysis of C-C Bonds; 4.8. Hydrogenolysis of N-O Bonds; 4.9. Hydrogenolysis of N-N Bonds; 4.10. Hydrogenolysis of Si-O Bonds; References
,
Chapter 5. Bond Breaking Reactions5.1. Breaking Carbon-Carbon Bonds: Decarbonylation; 5.2. Breaking C-O and C-H Bonds: Dehydration; 5.3. Breaking H-C Bonds: Dehydrogenation; 5.4. Breaking S-H Bonds; References; Chapter 6. Oxidations; 6.1. Oxidations with Hydrogen Peroxide; 6.2. Oxidations with O2, O3, and Other Reagents; References; Chapter 7. Immobilized Homogeneous Catalysts; 7.1. Immobilization by Different Methods; 7.2. Enantioselective Immobilized Catalysts; 7.3. Surface Organometallic Chemistry; References; Appendix; Author Index; Subject Index
,
English
Weitere Ausg.:
ISBN 0-12-651645-6
Sprache:
Englisch
