UID:
edocfu_9959234256302883
Umfang:
1 online resource (xxxii, 581 pages) :
,
digital, PDF file(s).
ISBN:
0-511-83177-3
,
1-316-17056-X
,
0-521-07890-3
,
1-316-17610-X
,
1-316-17379-8
,
0-511-94973-1
,
1-316-17797-1
,
0-511-52480-3
Serie:
Chemistry of solid state materials ; 2
Inhalt:
Protonic conduction in liquid electrolytes is commonplace but is relatively rare in solids. There is much interest worldwide in proton conducting solids, both from the scientific aspect, as materials with novel properties, but also for their possible applications in high-density solid-state batteries, sensors and other electrochemical devices. This book gives a comprehensive review of proton conductors, including theory, techniques, the materials themselves and applications.
Anmerkung:
Title from publisher's bibliographic system (viewed on 05 Oct 2015).
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Cover; Half-title; Title; Copyright; Contents; List of contributors; Preface; Symbols; I. HYDROGEN BOND AND PROTONIC SPECIES; 1 The hydrogen bond and chemical parameters favouring proton mobility in solids; 1.1 From ionic to protonic conduction; 1.2 The lone proton migration mechanism (translocation); 1.3 Proton-carrying mechanisms (the vehicle mechanism or V-mechanism); 1.4 Structural effects; 1.5 Chemical ''equilibrium'' and the ''ionic defect'': towards a chemical classification; 1.6 References; 2 Protonic species and their structures; 2.1 General introduction; 2.2 Proton hydrates
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2.3 Nitrogenous protonic species2.4 References; 3 Proton conductors: classification and conductivity; 3.1 Introduction; 3.2 Classification of protonic conductors; 3.3 References; 4 Defects, non-stoichiometry and phase transitions; 4.1 Introduction; 4.2 Ionic mobility and conductivity; 4.3 Electronic conduction and non-stoichiometry; 4.4 Water vapour pressure; 4.5 References; 5 Structural studies of proton conductors; 5.1 The structural situation; 5.2 Proton jumps; 5.3 Proton jumps and molecular reorientations; 5.4 Short hydrogen bonds; 5.5 Ordered and disordered networks; 5.6 References
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6 Hydrogen in metals: structure, diffusion and tunnelling6.1 Introduction; 6.2 Hydrogen absorption in metals; 6.3 Hydrogen diffusion and tunnelling; 6.4 A model of tunnelling; 6.5 Other theories of tunnelling; 6.6 References; II. MATERIALS: PREPARATION, STRUCTURES AND PROPERTIES; 7 Structure and characterization of hydrogen insertion compounds of metal oxides; 7.1 Introduction; 7.2 Preparations; 7.3 Thermodynamic aspects of hydrogen insertion; 7.4 Location of hydrogen in HxMOn; 7.5 Conclusions; 7.6 References; 8 High temperature proton conductors based on perovskitetype oxides
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8.1 Introduction8.2 Proton conducting solids at high temperature; 8.3 Preparation and properties of ceramics; 8.4 Verification of protonic conduction; 8.5 Conduction properties; 8.6 Proton formation in oxides; 8.7 Migration of protons; 8.8 References; 9 Highly ionic hydroxides: unexpected proton conductivity in Mg(OH)2 and homologues; 9.1 Introduction; 9.2 Non-hydrogen bonded systems; 9.3 Potential energy curve of the O-H oscillator; 9.4 Direct current proton conductivity measurements; 9.5 Proton conductivity results; 9.6 Proton carrier density on the conduction band; 9.7 Summary
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9.8 References10 Ice; 10.1 Introduction; 10.2 Structure of ordinary ice; 10.3 Defects and conduction mechanism; 10.4 Electrical properties of doped ice; 10.5 Conclusion; 10.6 References; 11 Anhydrous materials: oxonium perchlorate, acid phosphates, arsenates, sulphates and selenates; 11.1 Oxonium perchlorate; 11.2 Dihydrogen phosphates and arsenates, MH2XO4; 11.3 Hydrogen sulphates and selenates; 11.4 References; 12 Hydrogen behaviour in graphite-nitric acid intercalation compounds; 12.1 Graphite intercalation compounds; 12.2 Crystal structure of GNCs; 12.3 H mobility; 12.4 Conclusion
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12.5 References
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English
Weitere Ausg.:
ISBN 1-322-17753-8
Weitere Ausg.:
ISBN 0-521-38317-X
Sprache:
Englisch
