UID:
almafu_9958130912202883
Format:
1 online resource (533 p.)
ISBN:
1-299-46584-6
,
0-323-14690-2
Series Statement:
Organometallic chemistry v. 1
Content:
The Organic Chemistry of Nickel
Note:
Description based upon print version of record.
,
Front Cover; Organonickel Complexes; Copyright Page; Table of Contents; Preface; Introduction; References; Chapter I. Nickel Tetracarbonyl; I. Introduction; II. Preparation; III. Physical and Thermodynamic Data; IV. Structure and Bonding; V. Spectral Properties; VI. Reactions; VII. Mixed-Metal Carbonyl Clusters; VIII. Toxicity; References; Chapter II. Lewis-Base Nickel Carbonyl Complexes; I. Introduction; II. The Mechanism of Substitution; III. Substitution by Group IV-Donor Ligands; IV. Substitution by Group V-Donor Ligands; V. Substitution by Group VI-Donor Ligands
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VI. Substitution by Group VII-Donor LigandsReferences; Chapter III. Tetrakisligand Nickel Complexes; I. Introduction; II. Preparation; III. Structure; IV. Reactions; V. Spectroscopic Properties; VI. Tetrakistrifluorophosphine Nickel; VII Coordinatively Unsaturated Ligand-Nickel Complexes; References; Reviews; Chapter IV. Nickel Hydride, Nickel Alkyl, and Nickel Aryl Complexes; I. Nickel Hydride Complexes: Introduction; II. Monoligand Nickel Hydride Complexes; III. Bisligand Nickel Hydride Complexes; IV. π-Allyl-and π-Cyclopentadienylnickel Hydride Complexes
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V. Nickel Carbonyl Hydrides and Cationic Nickel HydridesVI. Nickel Alkyl and-Aryl Complexes : Introduction; VII. Ligand-Free Nickel Alkyl and -Aryl Complexes; VIII. Monoligand Nickel Alkyl and -Aryl Complexes; IX. Bisligand Nickel Alkyl and -Aryl Complexes; X. Tris- and Tetrakisligand Nickel Alkyl and -Aryl Complexes; XI. π-Allylnickel Alkyl and -Aryl Complexes; XII. π-Cyclopentadienylnickel Alkyl and -Aryl Complexes; References; Reviews; Chapter V. Nickel-Olefin and -Alkyne Complexes; I. Introduction; II. Bonding and Structure
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III. Nickel-Olefin Complexes Formed by Ethylene and Alkyl- or Aryl-Substituted OlefinsIV. Nickel Complexes Formed by Olefins Having Electron- Withdrawing Substituents; V. Nickel-Alkyne Complexes; VI. Nickel-π-Azo Complexes; VII. Nickel-Dioxygen Complexes; References; Reviews; Chapter VI. π-Allyl Nickel Complexes; I. Bonding Considerations; II. Spectroscopic Properties; III. Bis(π-Allyl)nickel Complexes; IV.π-Allyl Nickel X Complexes; V. π-Allyl NiX(Ligand) Complexes; VI. [π-AllylNi(Lig)3]+ Complexes; VII. π-Allylnickel π-Cyclopentadienyl Complexes; VIII. Hetero-π-Allylnickel Complexes
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IX. π-Cyclopropenylnickel ComplexesReferences; Reviews; Chapter VII. Cyclobutadienenickel Complexes; I. Introduction; II. Preparation of Cyclobutadienenickel Complexes; III. Structural Considerations; IV. Reactions of Cyclobutadienenickel Complexes; References; Reviews; Chapter VIII. π-Cyclopentadienyl Nickel Complexes; I. Bis-π-Cyclopentadienylnickel (nickelocene); II. π-Cyclopentadienylnickel Carbonyl and Isonitrile Complexes; III. π-Cyclopentadienylnickel Cluster Compounds; IV. π-C5H5NiX(Lig) and Related Complexes; V. Reaction of Nickelocene with Phosphorus and Sulfur Compounds
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VI. π-Cyclopentadienylnickel Nitrosyl
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English
Additional Edition:
ISBN 0-12-388401-2
Language:
English
