UID:
almahu_9948025735702882
Format:
1 online resource (362 p.)
ISBN:
0-444-60155-4
Content:
The Chemical Physics of Solid Surfaces
Note:
Description based upon print version of record.
,
Front Cover; Coadsorption, Promoters and Poisons; Copyright Page; Table of Contents; Preface; Chapter 1. Adsorbate-adsorbate interactions on metal surfaces; 1. Introduction; 2. The effective medium theory; 3. The direct electrostatic interaction; 4. Direct and indirect hybridization effects; 5. The elastic interaction between adsorbates; 6. Concluding remarks; Acknowledgements; References; Chapter 2. Theory of the coadsorption of H2O and CO with K on the Pt(111) surface; 1. Introduction; 2. Adsorption of H2O on Pt(111); 3. Adsorption of CO on Pt(111); 4. Adsorption of K on Pt(111)
,
5. Qualitative aspects of the coadsorption of K with H2O and CO6. Coadsorption of K and H2O on Pt(111); 7. Coadsorption of K and CO on Pt (111); Appendix: Charge transfer in closed shell systems; References; Chapter 3. Interaction between alkali metal adsorbates and adsorbed molecules (CO; H2O); 1. Introduction; 2. Model experiments of catalyst promotion; 3. Coadsorption: alkali metal and CO; 4. Coadsorption: alkali metals and H2O; 5. Coadsorption of alkali metals and other molecules; Acknowledgements; References; Chapter 4. Coadsorption of carbon monoxide and hydrogen on metal surfaces
,
1. Introduction2. CO + H on iron; 3. CO + H on iridium; 4. CO + H on nickel; 5. CO + H on palladium; 6. CO + H on platinum; 7. CO + H on rhodium; 8. CO + H on ruthenium; 9. CO + H on tungsten; 10. Summary; Acknowledgements; References; Chapter 5. Adsorption on bimetallic surfaces; 1. Introduction; 2. Atomic structure of bimetallic systems; 3. Metal-metal bonding in bimetallic systems; 4. Chemisorptive properties of bimetallic system; 5. Conclusions; Acknowledgement; References; Chapter 6. The chemical properties of alloy single crystal surfaces; 1. Introduction
,
2. Pd-Cu, Pd-Ag and Pd-Au single crystal surfaces3. Pt-Ti, Pt-Co, Pt-Ni and Pt-Fe single crystal surfaces; 4. Pt-Rh single crystal surfaces; 5. General discussion; Acknowledgements; List of abbreviations; References; Chapter 7. Promotion in ammonia synthesis; 1. Introduction; 2. Substrate dependence of nitrogen adsorption and ammonia synthesis; 3. Nitrogen dissociation on Fe - is it activated?; 4. Ammonia synthesis on single crystals; 5. Promotion - generalities; 6. The effects of promotion on nitrogen dissociation and ammonia synthesis; 7. Theoretical modelling; 8. Conclusions
,
9. Problems to be solved10. Future prospects; References; Chapter 8. Promotion in the Fischer-Tropsch hydrocarbon synthesis; 1. Introduction; 2. Catalysts and promoters for the Fischer-Tropsch synthesis; 3. The mechanism of the Fischer-Tropsch reaction; 4. Studies of the reaction using single crystal surfaces; 5. Conclusions; References; Chapter 9. Promoters and poisons in the water-gas shift reaction; 1. Introduction; 2. Sulfur poisoning of Cu catalysts; 3. Cesium promotion of Cu catalysts; 4. Conclusions; Acknowledgements; References; Chapter 10. Strong metal-support interactions
,
1. Introduction
,
English
Additional Edition:
ISBN 0-444-81468-X
Language:
English
