UID:
almafu_9959235749102883
Format:
1 online resource (1504 p.)
ISBN:
981-279-140-X
Series Statement:
World Scientific series in 20th century chemistry ;
Content:
In the course of his distinguished career spanning about half a century, George A. Olah, winner of the 1994 Nobel Prize for Chemistry, has been exceedingly prolific and has published more than 1000 scientific papers and 15 books and holds more than 100 patents. This invaluable volume contains about 250 papers selected for their breadth and current importance.
Note:
Description based upon print version of record.
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Volume 1 ; Contents; Preface; Part I. Early Studies; SYNTHESIS OF ORGANIC FLUORINE COMPOUNDS III. THE PREPARATION OF FLUOROMETHANOL; EXPERIMENTAL; SUMMARY; LITERATURE; SYNTHESIS OF ORGANIC FLUORINE COMPOUNDS, VIII. PREPARATION OF CHLOROFLUOROMETHANES (COMPOUNDS OF THE FREON TYPE); SUMMARY; LITERATURE; NITRYLBOROFLUORIDE AS A NITRATING AGENT; References; SILVER TETRAFLUOROBORATE AS A CATALYST IN ELECTROPHILIC AROMATIC SUBSTITUTIONS; Reference; Notiz uber die N-Formylierung von Aminen mit Formylfluorid
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Synthesis and Investigation of Organic Fluorine Compounds. XXIII. Preparation of Aromatic Fluorinated Esters as Local AnestheticsEXPERIMENTAL; Isolation of the Stable Boron Trifluoride-Hydrogen Fluoride Complexes of the Methylbenzenes; the Onium Salt (or σ-Complex) Structure of the Friedel-Crafts Complexes; Isolation of the Stable Boron Trifluoride-ethylfluoride and Boron Trifluoride-formylfluoride Complexes of the Methylbenzenes: Mechanism of the Friedel-Crafts Reactions; The Benzotrifluoride-Nitryl Fluoride-Boron Trifluoride Complex
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Synthesis and Investigation of Organic Fluorine Compounds. XXII. The Preparation of Newer 2-Fluoroethylurethan DerivativesEXPERIMENTAL; Part II. Electrophilic Aromatic Substitution; Aromatic Substitution. Part III. Alkylation of Aromatic Compounds by the Boron Trifuoride-catalysed Reaction of Alkyl Fluorides; EXPERIMENTAL; Aromatic Substitution. V. The Synthesis of a Protonated Toluene Tetrafluoroborate Complex; Experimental; Aromatic Substitution. VI. Intermediate Complexes and the Reaction Mechanism of Friedel-Crafts Aikylations and Acylations; Experimental
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Aromatic Substitution. VII. Friedel-Crafts Type Nitration of AromaticsIntroduction; Experimental; Acknowledgment; Aromatic Substitution. VIII. Mechanism of the Nitronium Tetrafluoroborate Nitration of Alkylbenzenes in Tetramethylene Sulfone Solution. Remarks on Certain Aspects of Electrophilic Aromatic Substitution; Introduction; Results; Discussion of Results; Experimental; Aromatic Substitution. XXII. Acetylation of Benzene, Alkylbenzenes, and Halobenzenes with Methyloxocarbonium (Acetylium) Hexafluoro- and Hexachloroantimonate; Introduction; Results and Discussion; Conclusions
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ExperimentalAcknowledgment; Friedel-Crafts Alkylation of Aromatics with 1-Chloronorbornane, 3-Halonoradamantane, and Fluorocubane via Their Reactive sp3-Hybridized Bridgehead Carbocations; Introduction; Results and Discussion; Conclusion; Experimental Section; Acknowledgment; Polyarenefullerenes, C60(H-Ar)n, Obtained by Acid-Catalyzed Fullerenation of Aromatics; Acknowledgment; Aromatic Substitution. XXXVIII. Chloromethylation of Benzene and Alkylbenzenes with Bis(chloromethyl) Ether, 1,4-Bis (chloromethoxy)butane, 1-Chloro-4-chloromethoxybutane, and Formaldehyde Derivatives
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Results and Discussion
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English
Additional Edition:
ISBN 981-02-2769-8
Language:
English
