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  • 1
    UID:
    gbv_640034128
    Format: Ill., graph. Darst
    ISSN: 1872-6151
    Content: This paper is an introduction to and an overview of papers presented in the Special Issue of Marine Geology "Methane seeps at the Hikurangi Margin, New Zealand". In 2006 and 2007, three research cruises to the Hikurangi Margin at the east coast of New Zealand's North Island were dedicated to studying methane seepage and gas hydrates in an area where early reports suggested they were widespread. Two cruises were carried out on RV TANGAROA and one on RV SONNE using the complete spectrum of state-of-the-art equipment for geophysics (seismic, sidescan, controlled source electromagnetics, ocean bottom seismometers and hydrophones, singlebeam and multibeam), seafloor observations (towed camera systems, ROV), sediment and biological sampling (TV-guided multi-corer, gravity-corer, grab, epibenthic sled), deployment of in-situ observatories (landers) as well as water column sampling and oceanographic studies (CTD, moorings). The scientific disciplines involved ranged from geology, geophysics, petrography, geochemistry, to oceanography, biology and microbiology. These cruises confirmed that a significant part of the Hikurangi Margin has been active with locally intense methane seepage at present and in the past, with the widespread occurrence of dead seep faunas and knoll-forming carbonate precipitations offshore and on the adjacent land. A close link to seismically detected fluid systems and the outcropping of the base of the gas hydrate stability zone can be found at some places. Pore fluid and free gas release were found to be linked to tides. Currents as well as density layers modulate the methane distribution in the water column. The paper introduces the six working areas on the Hikurangi Margin, and compiles all seep locations based on newly processed multibeam and multibeam backscatter data, water column hydroacoustic and visual data that are combined with results presented elsewhere in this Special Issue. In total, 32 new seep sites were detected that commonly show chemoherm-type carbonates or carbonate cemented sediment with fissures and cracks in which calyptogenid clams and bathymodiolid mussels together with sibloglinid tube worms live. White bacterial mats of the genus Beggiatoa and dark gray beds of heterotrophic ampharetid polychaetes typically occur at active sites. Bubble release has frequently been observed visually as well as hydroacoustically (flares) and geochemical analyses show that biogenic methane is released. All seep sites, bubbling or not, were inside the gas hydrate stability zone. Gas hydrate itself was recovered at three sites from the seafloor surface or 2.5 m core depth as fist-sized chunks or centimeter thick veins. The strong carbonate cementation that in some cases forms 50 m high knolls as well as some very large areas being paved with clam shells indicates very strong and long lasting seep activity in the past. This activity seems to be less at present but nevertheless makes the Hikurangi Margin an ideal place for methane-related seep studies in the SW-Pacific.
    In: Marine geology, Amsterdam [u.a.] : Elsevier Science, 1964, 272(2010), Seite 6-25, 1872-6151
    In: volume:272
    In: year:2010
    In: pages:6-25
    Language: English
    Author information: Bialas, Jörg
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  • 2
    UID:
    gbv_571729819
    ISSN: 0016-7037
    Content: Two sediment cores retrieved at the northern slope of Sakhalin Island, Sea of Okhotsk, were analyzed for biogenic opal, organic carbon, carbonate, sulfur, major element concentrations, mineral contents, and dissolved substances including nutrients, sulfate, methane, major cations, humic substances, and total alkalinity. Down-core trends in mineral abundance suggest that plagioclase feldspars and other reactive silicate phases (olivine, pyroxene, volcanic ash) are transformed into smectite in the methanogenic sediment sections. The element ratios Na/Al, Mg/Al, and Ca/Al in the solid phase decrease with sediment depth indicating a loss of mobile cations with depth and producing a significant down-core increase in the chemical index of alteration. Pore waters separated from the sediment cores are highly enriched in dissolved magnesium, total alkalinity, humic substances, and boron. The high contents of dissolved organic carbon in the deeper methanogenic sediment sections (50-150 mg dm-3) may promote the dissolution of silicate phases through complexation of Al3+ and other structure-building cations. A non-steady state transport-reaction model was developed and applied to evaluate the down-core trends observed in the solid and dissolved phases. Dissolved Mg and total alkalinity were used to track the in-situ rates of marine silicate weathering since thermodynamic equilibrium calculations showed that these tracers are not affected by ion exchange processes with sediment surfaces. The modeling showed that silicate weathering is limited to the deeper methanogenic sediment section whereas reverse weathering was the dominant process in the overlying surface sediments. Depth-integrated rates of marine silicate weathering in methanogenic sediments derived from the model (81.4-99.2 mmol CO2 m-2 year-1) are lower than the marine weathering rates calculated from the solid phase data (198-245 mmol CO2 m-2 year-1) suggesting a decrease in marine weathering over time. The production of CO2 through reverse weathering in surface sediments (4.22-15.0 mmol CO2 m-2 year-1) is about one order of magnitude smaller than the weathering-induced CO2 consumption in the underlying sediments. The evaluation of pore water data from other continental margin sites shows that silicate weathering is a common process in methanogenic sediments. The global rate of CO2 consumption through marine silicate weathering estimated here as 5-20 Tmol CO2 year-1 is as high as the global rate of continental silicate weathering.
    In: Geochimica et cosmochimica acta, New York, NY [u.a.] : Elsevier, 1950, 72(2008), Seite 3067-3090, 0016-7037
    In: volume:72
    In: year:2008
    In: pages:3067-3090
    Language: English
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