In:
Journal of Porphyrins and Phthalocyanines, World Scientific Pub Co Pte Ltd, Vol. 27, No. 01n04 ( 2023-01), p. 670-681
Abstract:
Comparison between a cobalt(II) porphyrin and a cobalt(III) corrole forming interfaces with a Ag(111) surface reveals that the ring size of the tetrapyrrole ligand influences the character of the interaction at the metal/organic interface. The corrole complex forms a stronger bond to the Ag(111) surface and engages in a much more pronounced interfacial charge transfer, compared to the porphyrin complex. The differences are explained by the open-shell character of the non-innocent corrole ligand and aromaticity-driven electron transfer.
Type of Medium:
Online Resource
ISSN:
1088-4246
,
1099-1409
DOI:
10.1142/S1088424623500608
Language:
English
Publisher:
World Scientific Pub Co Pte Ltd
Publication Date:
2023